低氧低分压环境下泡塑吸附-石墨炉原子吸收光谱法测定化探样品中的痕量金.pdfVIP

2010 年6 月 岩矿测试 Vo1. 29 , No.3 June 2010 ROCK AND MINERAL ANALYSIS 282 叫 286 文章编号: 0254 -5357(2010)03 -0282 …05 低氧低分压环境下泡塑吸附-石墨炉原子吸收光诸法 测定化探样品中的痕最金 五机，邵蓓，邬罔栋，李明礼 (回藏地勘局中心实验案，回藏拉萨时∞33) 3 摘要:针对西藏低氧低分压环境下痕量食的测定，探讨了溶矿介质、解脱时间、吸附温度、Fe -t加入量等对 3 守在溶矿和吸附过程中的重要作用。方法检 删定结果的影响。确定了最佳测定各件，并较详细讨论了 Fe 出限为 O. 102 nglg ，测定范罔为 0.24 时 3∞ nglg ，准确度( .11gC , n =12) 为 0.01 阳 0.03 ，精密度(RSD， n =12) 为1. 61% 阳 7.33% ，很好地解决了西藏地区低就低分压低源环境下痕量金测定的技术难题。 关键词:低氧低分压;化探样品;痕量金;石墨炉原子吸收允谱法 中团分类号: 0614.123; 0657.31 文献标识码:B Determination of Trace Gold in Geochemical Samples by Graphite Furnace Atomic Absorption Spectrometry with Polyurethane Foam Preconcentration under Hypobaric Hypoxia Condition WANG Zhu , SHAO Bei , WU GlW -dong , LI Ming-li (Central Laboratory of Tibet Geol吨ical Exploration Bureau , Lhasa 850033 , China) Abstract: In order to determine trace gold in geochemical SaJ叩les by GF-AAS under hypobaric hypoxia condition in Tibetan areas , the effects of digestion solvents , adsorption temperature , desorption time and dosage of Fe3 + on the determination were discussed. GF-AAS measurement condition w剧 optimized and the catalytic mechanism of Fe3 + during sample processing and pre嗣concentration steps was studied in detail. The detection limit of the method for Au w嗣 0.102 nglg with dynamic range ofO. 24 -300 nglg. 响le accuracy of the meth叫 W嗣 0.01 - O. 03 (àlgC ,n =12) wi出 precision of 1. 61 % -7.33% RSD (n =12). The method has been applied to the determÍnation of trace gold in geochemical samples in Tibetan with satisfactory results. Key words: hypobaric hypoxia condition; geochemica