内插TOC系数法测定水体中COD研究.pdfVIP

第 37 卷第4 期 2即7 年8 月 山东大学学报(工学版) Vol.37 No.4 JOURNAL OF SHANDONG UNlVERSITY (ENGINEERING SCIENCE) Aug. 组刃7 文章编号:1672-3961 阳凹}俱.QI08-lO 内插 TOC 系数法测定水体中 COD 研究 刘云，邱晓国 (山东省环境监测中心站， 山东济南 25∞l3) 摘要:运用废水样JY归一化处理理念，基本解决了废水TOC 测定中悬浮物、共存离子(硫酸根、硝酸根、磷酸根、 氯离子、硫离子等)、高含量元机碳(lC) 、高碱高盐等因素的千扰，实现了废水 TOC 的正常测定.运用测定区间限 定化理念研究了全省造纸、酿酒、印染、农药、制药、淀粉、味精、橡胶、化工、焦化、电厂等主要行业废水，以及污水 Cr相关关系.在归一化和限定化条件下，而 与 处理厂废水和地表水、饮用水等水体TOC 与 COD C COD Cr具有良 好的相关关系，由此提出了内插 TOC 系数法这一新的 COD 测定方法. 关键询:系数法;总有机碳;化学需氧量;相关性;测定 文献标识码:A 中圄分类号:X52;X703 COD determination by interpolation of the TOC coet1icient method 山Yun， QIU Xiao-guo (Shandong Provincial Environmental Monitori吨 Centre ， Jinan 25∞13 ， China) Abstract: 咀蛇 Ìnterference in TOC detennination of wastewater was basically solved by use of 也e conce酬。n of nonnalization method in sample treabnent , such as suspended solids , coexistence ions (sulfate , nitrate , phos- pha怡， chloride , su监ll ， etc.) , high levels of ino耶nic carbon (IC) , high alkalî and high-salt. The detennÎ- nation of TOC in wastewater is nonnalized. Also出e correlation between TOC and CODCr in water in Shandong pro白nce was studied. For example ，由e wastewater of paper making , breweries , dyeing , pesticides , phanna- ceutîcals , starch , MSG , rubber , chemicals , coke , power plant , sew略:e treatment plant and surface water , and 也i址íng water. It proves that TOC has a very 伊od correlation wi