农产品中痕量钒的测定研究.pdfVIP

安徽农业科学，Joumal of Anhui Agri. Sci. 2011 ,39 (36) :22574 - 22575 责任编辑李菲菲责任校对李岩 农产品中痕量饥的测定研究 李跃华l 气郭洁1 ，杨志毅1* (1· 大理学院药学学院，云南大理671棚;2. 云南大学化学科学与工程学院，云南昆明 65棚1 ) 摘要 [目的]建立一种测定痕量叙，(V) 的新方法。[方法]在拧稼酸介质中，利用阻rO，氧化拧稼黄褪色反应测定痕量机。首先绘制吸 收曲线，选择测定波长，然后研究反应的最佳条件包括拧稼酸用量、KBrO，溶液和拧棒黄溶液用量以及反应的温度与时间，确定线性范 围及检出限，测定表观，活化能，并研究共存离子的影响。[结果]选择测定波长为 430 nmo 在拧棒酸介质中，机对阻rO，氧化拧橡黄具 有强烈的催化作用。反应的最佳条件为拧橡酸用量3.5 mglL， KBrO，溶液2.5 时，拧橡黄2.5 mglL，反应温度93 C，反应时间 16 min。 测定痕量机方法的线性范围为 0-40μ岳IL， 方法检出限为 3.8 ngirnl ， RSD 为 2.369岛。[结论]采用该方法测定农产品中痕量机具有灵 敏度较高、抗干扰离子能力强、操作简俊的特点。 关键词催化光度法:机(V) ;拧襟黄 中固分类号 5312 文献标识码 A 文章编号 0517 -6611 (2011 )36 -22574-02 Study 00 Determinatioo of Trace Vanadium in Agricultural Products LI Yue也ua et aI (School of Phannacy , Danli Unive四i町， Danli , Yunnan 6710∞) Abstract [ Objective] The study aimed to establish a new method of determining the trace vanadium. [Method] In由e citric acid medium , the fading reaction with 由e KBrO, oxidation of citric yellow w田 used for the determination of trace vanadium. Firsùy , the absorption cu凹ew田 drawn ωchoose 血e measuring wavelength , and then ，由e optimal conditions including 出e dosages of citric acid , KBrO, solution and citric yellow solution and the reaction temperature and the time were studied. Tthe linear range and detection limit were confirmed ，由e apparent ac- tivation energy w臼 determined ，时也e influence action of the coexistence ions was studied. [Result] The measuring wavelength was selected 幽 430 nm. In the citric acid medium , the vanadium had strong 也e catal严ic role in the KBrO, oxidation of citric yellow. 四e optimum condi- tions for the reaction w幽幽follows: the citric acid dosage of3. 5 mglL , KBrO, solution of2. 5 rnl and citric yellow dosage of2. 5 mglL , reac- tion temperature of 93 C and reaction time of 16 min. The linear ran