减小水样浊度对废水中六价铬测定结果影响的方法探讨.pdfVIP

2012 年2 月 岩矿测试 Vol. 31 , No.1 February 2012 ROCK AND MINERAL ANALYSIS 172 -177 文章编号: 0254 -5357(2012)01 -0172-06 减小水样浊度对废水中六价格测定结果影响的方法探讨 赖永忠 (汕头市环境保护监测站，广东汕头 515041) 摘要:建立了二苯碳耽二脐分光光度法测定废水中 Cr( 飞在)的三泼长法，减小了水样浊度的影响，但不能减 小除浊度之外的其他干扰，对Cr( VI) 测定结果的影响。三波长法的测定波长为 540 nm， 4ωnm 和 660 nm 为 参比波长，方法检出限为 0.3μglL( 3. 143s) ， 拟合方程的线性关系为0.9998 ， 8.0μglL 标准点水样测定结果 的相对标准偏差(RSD ， n =7) 为1. 44% ，实际样品加标回收率均值为 84.8% -93.8% 0 与单波长法相比， 三波长法提高了二苯碳耽二脐分光光度法测定水中 Cr( 回)的精密度和准确度，与浊度补偿法相比具有较好 的精密度，可减轻分析人员的工作量。三波长法适用于较低浊度废水(显色后样品本底在540 nm 处的吸光 度小于0.1∞0) 中 Cr( VI) 的直接比色分析，浊度较高的样品应适当稀释后显色测定。 关键词:六价恪;二苯破耽二脐分光光度法:浊度;三波长分光光度法;废水 中图分类号: 0657.3; 0614.611 文献标识码:A EfTect Elimination of Turbidity on Diphenylcarbazide Spectrophotometric Measurement of Cr ( VI) in Waste Waters lAI Yong-zhong (Shantou Enviromental Monitoring Station , Shantou 515041 , China) Abstract: Triplex-wavelength spectrophotometric methoos using diphenylcarbazide 皿 a chromogenic re吨ent w脑 established to eliminate the interference of turbidity for determining Cr( VI) in waste water. However , this methoo could not be used ωeliminate the effect of 0由er factors on Cr( VI) except for turbidity. In the triplex-wavelength spectrophotometric me出00 ， the measuring wavelength w，幽 540 nm , and the 陀ference wavelengths were 460 nm and 660 nm. The triplex-w町elength spectrophotometric methoo had a g∞d correlation coefficient (r = 0.9998) and precision (RSD 1. 44% , for 回ven 8.0 J.Lg/L standard samples). The detection limit (LD = 3. 143s) w田 0.3 f.LglL.咀le average value of 陀coveries in waste water samples were in the range of 84. 8% - 93.8% using an intemal standard. Comp缸edwi由由e single-wavelength spectrophotometric me由00 ，由e triplex-wavelength spectrophotometric m