利用发光量子点探针测定多环芳烃和酞酸酯污染物的研究.pdfVIP

来守军等 利用发光量子点探针测定多环芳经和酷酸菌污染物的研究 利用发光量子点探针测定多环芳怪和 酥酸醋污染物的研究骨 来守军1.2 贾夭明3 关晓琳3 林俊杰2 杨季冬2 陈 星2 左 波2 (1.兰州文理学院化工学院，甘肃 兰州 730000; 2. 三峡库区水环境演变与污染防治重点实验室，重庆 404100; 3. 西北师范大学化学化工学院，甘肃 兰州 730070) 摘要 以 CdSe/CdS 量子点CCdSe/CdS QDs)为原料，对其进行硅统氨基化表面修饰，合成了具有水溶性的左右量子点(CdSe/ Cd5-Si-NH2 QDs)探针，基于量子点与持久性有饥污染物(POPs)发生共振能量转移及偶联反应等过程而导致荧光变化的现象，分 别利用荧光光谱、三维荧光光谱和荧光猝灭原理测定花、荧惠和歌酸醋浓度。结果表明，构建的测定方法对花、荧慧和欧酸醋的检测 限均达到pg/L水平，将 CdSe/Cd5-Si-NH QDs 应用于三峡库区(万州段〉水体茂、荧惠和ftt 酸酶含量的测定，3 种污染物的力目标回收 2 率为89.5%-10自.4%，达到了定量灵敏测定的要求，根据分析结果，对三峡库区污染物的来源进行了分析。 关键词多环芳经歌酸葡量子点荧光探针测定 001: 10.15985/j.cnki.1001-3865.2016.1 1.004 The detennination of 阳Ilycyclic aromatic hy由唰泪rbon and phthalate ester ~鼠~ωlight-emitti吨 quan阳m dots probe LAI Shouj un l. 2 ,]lA Tianming ,GUAN Xiaolin 3 ,LIN Junjie 2 ,YANG Jidong 2,CHEN Xing 2 ,ZUO B02 . (1. School 01 Chemical Engineering ,Lanzhou University 01 Arts and Science. Lanzhou Gansu 730000; 2.Key Laboratory 01 Wa- ter Environment Evolution and Pollution Control in Three Gorges Reservior. Chongqing 404100; 3.College 01 Chem- istry and Chemical Engineering ,Northwest Normal University. Lanzhou Gansu 730070) Abstract , The water soluble light-emitting quantum dots (CdSe/Cd5-Si-NH 2 QDs) probe was synthesized by surface modification of CdSe/CdS QDs using silane amination. The resonance energy transfer and coupling reaction between persistent organic pollutants (POPs) and quantum dots would cause fluorescence changes. With the help of fluorescence spectrum. three-dimensional fluorescence spectrum ,and fluorescence quenching technology ,a novel meth od was proposed to detect 3 typical POPs (pyrene. fluoranthene and phthalate