原子荧光法测定食品总砷的前处理方法探讨.pdfVIP

2013. 协1.34， No. 1O 177 ※分析检测 画面融事 原子荧光法测定食品总呻的前处理方法探讨 屈明华，汤富彬，倪张林 (中国林业科学研究院亚热带林业研究所，国家林业局经济林产品质量检验检测中心(杭州)，浙江富阳 3114∞) 摘 要:通过研究两种不同混酸(硝酸-高氯酸和硝酸-高氯酸-硫酸)对小麦粉、蔬菜粉、海藻粉进行前处理，原子荧 光法对其总碑进行测定。结果表明:测定小麦粉、蔬菜粉中总牌时，两种前处理方法得出的结果基本-致:对海藻 粉样品，使用高沸点硫酸处理，消化效果明显提高，使用硫酸消化海藻样品测定结果通过了国际能力验证(比利时 IMEP 112)的检验。小麦粉、蔬菜粉样品中总阔的存在形式主要以无机碑形态存在，低沸点酸适合碑存在形态相对 简单的样品，但对于富含有机呻的藻类样品，只有使用高沸点硫酸进行处理，藻类中有机碑才能充分分解转化为无 机碑，从而为原子荧光光谱仪准确测定。 关键词:原子荧光光度法:小麦:蔬菜:海藻:前处理:总呻 Different Pretreatments for Oetermination of Total Arsenic in Foods by Atomic Fluorescence Spectrome缸y QU Ming-hua , TANG Fu-bin , NI Zhang-lin (Research Institute of Subtropical Forestry , Chinese Academy of Forestry , Quality Testing Center for Edible Forest Products of State Forestry Adrninistration (Hangzhou) , Fuyang 311400, China) Abstract: An atomic ftuorescence spectrometric (AFS) method was developed for the deterrnination of total arsenic in wheat, vegetable and algae. Two sample pretreatrnents were proposed based on digestion with either HNO HCI04 or HN0 - r 3 HCI0 -H S0 • Basically similar results were obtained by both sample pretreatments. Improved digestion of algae was 4 2 4 achieved by using H S0 due to its high boiling point , and the validity of this digestion method was confimed by proficiency 2 4 testing according to IMEP-112: Total and Inorganic Arsenic in Wheat, Vegetable Food and Algae. The chernical speciation of inorganic 缸senic was dorninant in wheat and vegetable. Low boiling point acid was suitable for digestion of s缸nples with simple chernical speciation of ars巳ni