论文 ti-zr-ni 系准结晶の水素吸收と构造 hydrogen absorption and .pdfVIP

Ti-Zr-Ni * ** * ** 930-8555 3190 Hydrogen absorption and structure of Ti-Zr-Ni quasicrystals Y.OISHI, M.HARA*, T.OKABE** Faculty of Science and Engineering, Toyama University Graduate School Hydrogen Isotope Research Center, Toyama University* Faculty of Science, Toyama University** Gofuku3190, Toyama 930-8555, JAPAN (Received April 10, 2002; Accepted December 20, 2002) Abstract Results of transmission Electron Microscopy of expansion of a lattice accompany hydrogen absorption are reported. The icosahedral phase (i phase), the crystal approximant phase (w phase) and the Laves phase in a Ti-Zr-Ni alloy demonstrated hydrogen absorption from the gas phase at a temperature of 300 and a pressure of 10 Torr. The i phase, the w phase and the Laves phase remained after the hydrogen absorption, giving a hydrogen atom-to-metal atom ratio ([H]/[M]) of 1. 14. The rate of expansion of lattice depended on the lattice structure. The rate of expansion of the lattice was analyzed, and it was found that the ability of the w phase to absorb hydrogen is greater that of the i phase. Expansion of a lattice of the i phase and that of the w phase are isotropic. The results indicate that hydrogen is homogeneously distributed. 1. 1 1984 ShechtmanAl6Mn 5 1997 Ti-Zr-Ni 2 3 (i) Ti-Zr-Nii i w 53 4 Ti-Zr-Ni