可控交联聚芳醚酮改性电子束固化环氧树脂结构与性能的研究 - 材料工程.pdf

28 / 2003 11 St udy on t he St r uct ur e and M ech anical P r oper t ies of t he Elect r on Beam Curing Epo xy Res in M odif ied by t he Cont r ollable Cross linking P oly A r yl Et her Ket one 1 2 ( 1 310027; 2 100095) 1 2 Q IN Ming Y I X iao -su ( 1 D ep art ment of Po lymer Science and Engineering Zhejiang U niver sit y Hang zhou 310027 China; 2 Instit ute of A eronaut ical Mat erials Beijing 100095 China) : ( CCPA E K ) CCP A EK E B-3 150 -3 DM T A k G y E B E B E B-3 T GA CCPA E K E B-3 : ; ; : T B332: A : 100 1-43 81 ( 200 3) 11-002 8-04 : - ( ) Abstract T he elect ron beam EB cro ssl inking beh avior of a novel co nt roll able cr osslinking Po ly A ryl Ether K eto ne ( CCPA EK) w as st udied . T he st ru ct ure and mech anical prop ert ies o f t he EB cur- able epoxy resin named EB-3 w hich modified by t he CCP A EK w ere explor ed . T he unit ary glas s t ransition t emp er at ure of t he modif ied EB-3 cured at 150k Gy EB dose w as bet w een t hose of unm odi- fied EB-3 and CCP A EK by mean s of dynamic m ech anical t hermal analysis ( D MT A ) . T he modified EB-3 sp ecimens show ed t ough fract ure ch aract ers according t o the SEM phot os and