尾气余热制氢汽油机的燃烧机理构建与简化 - 北京工业大学学报.pdf

第42卷 第12期 北 京 工 业 大 学 学 报 Vol.42 No.12 2016年 12月 JOURNAL OF BEIJING UNIVERSITY OFTECHNOLOGY Dec. 2016 尾气余热制氢汽油机的燃烧机理构建与简化 冯是全,胡以怀 (上海海事大学商船学院,上海摇 200120) 摘摇 要:为了对尾气余热制氢汽油机的缸内燃烧进行仿真,发展了适合这一燃烧形式的反应机理. 分析了重整气 的组分,选用甲烷机理GRI3郾0 和汽油替代燃料机理,构建了包含334种组分和1672步反应的可用于汽油/ 重整气 燃烧仿真的详细机理,并通过直接关系图法对构建的详细机理进行了简化,最后得到了包含40种组分和171步反 应的简化机理. 通过一维汽油机模型对该简化机理进行了验证,验证内容包括缸内平均压力、压力误差、缸内平均 温度、温度误差、放热率、放热率误差以及OH的摩尔分数,验证了简化机理的有效性. 关键词:汽油机;重整气;甲烷;汽油;直接关系图 中图分类号:TK46 文献标志码:A 文章编号:0254-0037(2016)12-1901-06 doi:10.11936/ bjutxb2016030018 Construction and Simplification of the Combustion Mechanism of Gasoline Engine With Steam Reforming With the Heat of Exhaust Gas FENG Shiquan,HU Yihuai (Merchant Marine College,Shanghai Maritime University,Shanghai200120,China) Abstract:To simulatethe combustion inthe cylinder of gasoline enginewith steamreforming,a detailed mechanism was developed. The mechanism of GRI 3郾0 and gasoline surrogate were used for the construction of the detailed mechanism according to the componentsin syngas. The detailed mechanism, with334 species and 1672 reactions,was reduced with direct relation graph method to form a reduced mechanism with 40 species and 171 reactions. The reduced mechanism was verified by the one dimensional gasolineenginemodelby thetest of theaveragetemperature,thetemperatureerror,theheat release rate,the heat release rate error and the difference between OH concentration. Results show good agreement of the validation of detailed mechanism and reduced mechanism. Key words:gasoline engine;syngas;methane;gasoline;directed relation graph 摇 摇 国内外很多学者开展了发动机替代燃料的研究 分离出来,并供给发动机燃烧做功,能较好地解决氢 工作,液化天然气、液化石