哒螨灵_层状双金属氢氧化物杂化物的合成及表征.pdfVIP

45 9 ( ) 2010 9 V ol. 45 No. 9 Journal of Shandong U niversity( N atural Science) Se . 2010 : 2010) - * 张少杰, 徐洁, 侯万国 ( , 266042) :在乙醇 - 水混合溶剂中采用共沉淀法将非离子型疏水性农 哒螨灵插入镁铝层状双金属氢氧化物( layered double hydrox ides, LDH s)层间, 制备出哒螨灵- LDH s杂化物依据哒螨灵分子大小和杂化物的层间通道高度推 测, 哒螨灵分子是沿长轴方向与层板成一定倾斜角度以单层方式排列于 LDH s层间释放动力学研究表明, 释放 过程符合准二级动力学方程, LDH s颗粒内扩散是释放控制步骤; 哒螨灵- LDH s杂化物具有明显的农 缓释性能, 有望成为一种新型农 缓释剂 :层状双金属氢氧化物; 哒螨灵; 杂化物; 释放; 农 : O 657 : A Synthesis of yridabenlayered double hydrox ides hybrids using the co reci itation m ethod * ZHANG Shaojie, XU Jie, HOU W anguo ( C ollege of Chem istry and M olecular Engineering, Q ingdao Un iversity of S cience and Techno logy, Q ingdao 266042, Shandong, Ch ina) A bstrac t: A nonionic and oorly w aterso lub le esticide, yridaben, w as intercalated into the gallery of layered double hydroxides ( LDH s) using the co reci itation m ethod in an ethanolw ater m ixed solvent m ed ium, obtaining yridaben LDH s hybrids. According to the gallery heigh t of yridabenLDH s and sizes of the yridaben m olecule, a robab ly m or ho logy of yridaben m o lecules in the gallery of LDH s suggested that yridaben m olecu les are arranged as a m onolayer w ith the long axis tilted to the LDH s layers. The release kinetics of yridaben from the hybridsw as investigated in an eth anolw ater solution, and itw as found that the release rocessm ay fit the seudosecondorder release k inetics and the dif fusion thro