水热法制备zno 二维周期有序孔结构薄膜 - 化学通报.pdf

《化学通报》在线预览版 水热法制备 ZnO 二维周期有序孔结构薄膜 1, 2 1 1 ,* 2 张荫民 蓝鼎 王育人 王凤平 1 2 ( 中国科学院力学研究所 北京 100080 北京科技大学 北京 100083) 摘 要 在由溶胶-凝胶法制备的纳米 ZnO 薄膜衬底上，以 Zn(NO ) ·6H O 和六次亚甲基四胺(HMT)等摩尔浓 3 2 2 度配制成前驱体溶液，在单层聚苯乙烯(PS)微球模板辅助下，采用水热法制备了具有规则多孔结构的 ZnO 薄膜。 探讨了 PS 微球作为模板对 ZnO 纳米棒生长的限制作用以及柠檬酸钠在水热制备方法中对晶体生长的影响。利 用扫描电子显微镜(SEM)和 X 射线衍射(XRD)表征了水热反应后所得二维有序 ZnO 膜表面形貌和取向性，测量 了ZnO 薄膜的光致发光(PL)光谱并研究其相应机理。 关键词 ZnO 水热法 溶胶-凝胶 反蛋白石结构 Hydrothermal Synthesis of 2D Ordered Macroporous ZnO Films Zhang Yinmin1, 2 Lan Ding1 Wang Yuren1,* Wang Fengping2 1 2 ( Institute of Mechanics, Chinese Academy of Sciences, Beijing 100080; University of Science and Technology Beijing, Beijing 100083) Abstract The ZnO films with 2D ordered macroporous structure were successfully fabricated through hydrothermal crystal growth of ZnO on the ZnO substrate covered with a monolayer of polystyrene(PS) spheres as porous structure template. The precursor solution of ZnO hydrothermal crystal growth were prepared by equimolar solution of Zn(NO ) ·6H O and hexamethylenetramine (HMT). The confinement effect of the PS spheres template on the growth 3 2 2 of ZnO nanorods and also the influence of sodium citrate on the ZnO crystal growth had been studied. The film surface morphology and the preferential growth of ZnO crystal were investigated by scanning electron microscopy (S