固相萃取-气相色谱法测定饮用水中15种农药残留.pdfVIP

中国卫生检验杂志2007年12月第l7卷第12期 Chinese Journal of Health Laboratory Technology，Dec 2007；Vol 17 No 12 2147 【论著】 固相萃取一气相色谱法测定饮用水中15种农药残留 张潜 ，黎源倩¨，陈刚。 (1．成都市疾病预防控制中心，成都 610021； 2．四川大学华西医学中心公共卫生学院，成都 610021；3，四川省双流县疾病预防控制中心，成都 610200) [摘要】 目的：建立同时检测饮用水中15种农药残留的固相萃取一气相色谱分析方法，所检测的农药包括5种有机磷、 5种有机氯、5种拟除虫菊酯。方法：利用ENVI—C18固相萃取小柱提取水样中农药，小柱用甲醇和水活化，丙酮一正己 烷(25：75，v／v)洗脱，浓缩后用GC—ECD测定。对水样前处理和色谱条件等进行了优化选择。结果：有机磷、拟除虫菊 酯在0．05 1，0 rul，有机氯在0．01～0．2 rul浓度范围内有良好的线性，方法检出限为0．0021～0，032 L。样品 平均加标回收率为70．2％一104．0％，精密度以平行样品的相对标准差(RSD)表示，为2．2％～13，0％。结论：本方法具 有操作简单、准确、灵敏、重现性好、安全环保等优点，适用于饮用水中部分拟除虫菊酯、有机氯及有机磷的检测。 [关键词] 固相萃取；农药残留；气相色谱法；饮用水 [中图分类号] 0657．7’1 [文献标识码] A [文章编号] 1004—8685(2007)12—2147—04 Multi——residue determination method of pesticides in drinking water by solid——phase ex- traction followed by gas chromatography th electron capture detector Zhang Qian’ ，Li Yuan．qian“，Chen Gang。 (1．Chengdu Center for Disease Control and Prevention，Chengdu 610021，China；2，West China School of Public Health，Sichuan University，Chengdu 610021，China；3，Shuangliu Center for Disease Control and Prevention，Chengdu 610200，China) [Abstract] Objective：A multiresidue method based on solid—phase extraction and gas chromatography with electron capture detector Was developed for the simultaneous detmination of 1 5 pesticides in drinking water．Methods：The extraction procedure Was carried out in ENVI—C18 columns preconditioned with methanol and water．The subsequent elution of pesticides Was per- formed with a mixture of acetone—hexane(25：75．v／v)prior to the determination by gas chromatography witlI electron capture detector．Results：Average recoveries flor aU the pesticides studied were higher than 70％ and relative