微波消解-AFS法测定婴幼儿配方奶粉中硒的测量不确定度评定.pdfVIP

禽矗研究与持1: 2016 年6 月 撞测分析 Food Research And Development 第 37 卷第 11 期 139. - 001: 10.3969/j.issJi.lω5-6521.2016.11.032 微波消解-AFS法测定婴幼儿配方奶粉中晒的 测量不确定度评定 崔颖，葛含光，温华蔚，倪松 (天津出人境检验检疫局动植物与食品检测中心，天津3∞461) 摘 要:建立微波消解-AFS 法测定婴幼儿配方奶粉中涌含量的测量不确定度的测量模型，根据模型分析并计算不确 定度各个分量、结果的不确定度以及扩展不确定度。结果表明，引起测量不确定度的最主要来源是测定C 值时用最 小二乘法拟合标准工作曲线所引入的不确定度。计算得到在婴幼儿奶粉中局含量为 0.310 mglkg 时，扩展不确定度为 o.ω6mglkg，包含因子 k 为 2。该方法适用于婴幼儿配方奶粉中局含量的测量不确定度评定。 关键词:测量不确定度;原子荧光光谱法;属;婴幼儿配方奶粉;微波消解 Uncertaintiy Evaluation in the Measurement of Selenium in MiIk Powder for Infant and Young Children wi也Microwave Digl臼伽In-AFS CUIYi吨， GE Han-guang , WEN Hua-wei , NI Song (Tianjin Entry-exit Inspection and Quarantine Bureau ,Tianjin 3∞461 ， China) Abstract: A measurement model was established , the independent uncertainty , standard uncertainty and ex- panded unce血inty coming from analysis procedure were obtained. 咀le m句or source of the unce由inty was 由e calibration curve calculated on the basis of the principle of method of least s甲1缸es when determining C. As sele- nium content in milk powder for infant and young children was 0.310 mg/kg , the expanded uncertainty w嗣 0.046 mg/kg and the cover吨e factor k was 2. This me也od was suitable for evaluating the uncertainties in 出e measurement of selenium in milk powder for infant and young children. Key words: measurement uncertainty; atomic fluorescence spectrome町 (AFS); selenium; milk powder for infant and young children; microwave digestion 在报告测量结果时不仅要给出测定的量值是多 验室日常检测能力与条件，进行