氢化物原子荧光法测定生活饮用水及其水源水中的铅.pdfVIP

中国卫生检验杂志2007年12月第l7卷第12期 Chinese Journal of Health Lal~ratory Technology，Dec 2007；Vol 17 No 12 2199 【化学测定方法】 氢化物原子荧光法测定生活饮用水及其水源水中的铅 刘丽萍，张妮娜，张勐 (北京市疾病预防控制中心，北京 100013) [摘要] 目的：建立简便、灵敏、准确的生活饮用水及其水源水中铅的测定方法。方法：采用氢化物原子荧光法测定生活 饮用水及其水源水中的铅。结果：实验表明，方法的线性范围0～70 g／L，相关系数r优于0．9990，方法的检出限为 0．084 t．rg／L，用相对标准偏差考察方法的精密度，RSD均小于4．0％，用加标回收和标准物质考察方法的准确性，加标回 收率均在85．0％～116．5％之间，测定了国家标准参考物GSBZS009—88，测定值均在标准值范围内。结论：该方法简便、 灵敏、准确，适用于生活饮用水及其水源水中铅的测定。 [关键词] 氢化物原子荧光法；饮用水及其水源水；铅 [中图分类号] 0657．31 [文献标识码] A [文章编号] 1004—8685(2007)12—2199—03 Determination of lead in drinking water and source water by hydride generation atomic fluorescence spectrometry Liu H-ping．Zhang Ni一， ，Zhang Meng (Beijing Center for Disease Control and Prevention，Beijing 100013，China) [Abstract] Objective：To establish an simple，sensitive and accurate analytical method to determine lead in drinking water and source water．Methods：Hydride generation atomic fluorescence spectrometry was applied to determine lead in drinking water and source water．Results：It showed that the linear range of this method was 0～70 g／L The linear correlation factor for lead was higher than 0．9990．Recoveries of spiked samples were in the range of 85．0％ ～1 16．5％ and RSD was lower than 4．0％．And the results showed close agreement with the reference values in standard reference materials of GSBZS009—88．Conclusion： The method is simple，rapid，sensitive and accurate，which can meet the demand for lead analysis in drinking water and source water． [Key words] Hydride generation atomic fluorescence spectrometry；Drinking water and source water；Lead 铅是可在人体和动物组织中蓄积的有毒金属，对人体中 I 材料与方法 枢和周围神经系统，血液及造血系统和肾脏等都有严重危害， 1．1 方法原理 铅可导致贫血、神经机能失调