文献翻译,内量子效率为100%体相异质结太阳能电池.docVIP

Bulk heterojunction solar cells with internal quantum efficiency approaching 100% 内量子效率接近100%的体相异质结太阳能电池 We report the fabrication and measurement of solar cells with 6% power conversion efficiency using the alternating co-polymer, poly[N-900-hepta-decanyl-2,7-carbazole-alt-5,5-(40,70-di-2-thienyl-20,10,30-benzothiadiazole) (PCDTBT) in bulk heterojunction composites with the fullerene derivative [6,6]-phenyl C70-butyric acid methyl ester (PC70BM). The PCDTBT/PC70BM solar cells exhibit the best performance of any bulk heterojunction system studied to date, with JSC510.6 mA cm22, VOC50.88 V, FF50.66 and he56.1% under air mass 1.5 global (AM 1.5 G) irradiation of 100 mWcm22. The internal quantum efficiency is close to 100%, implying that essentially every absorbed photon results in a separated pair of charge carriers and that all photogenerated carriers are collected at the electrodes. 我们报道了一种能量转换效率为6%的太阳能电池的制作和测量，这种太阳能电池体相异质结材料为PCDTBT和PC70BM。这种PCDTBT/PC70BM材料体相异质结电池是目前所有体相异质结太阳能电池中性能最好的，在AM1.5G、100 mW/cm-2 光照下，短路电流10.6mA cm-2, 开路电压50.88 V, 填充因子50.66 、效率56.1%。 Polymer bulk heterojunction (BHJ) solar cells based on composites of an electron-donating conjugated polymer and an electron-accepting fullerene offer promise for the realization of a low-cost, printable, portable and flexible renewable energy source1–4. Although BHJ solar cell performance has steadily improved, with power conversion efficiencies (PCE;he) approaching 5%, further improvements in efficiency are required for largescal ecommercialization5–7. 聚合物体相异质结太阳能电池是基于电荷给提共轭聚合物和电荷受体富勒烯混合制作的。这种太阳能电池具有成本低、可印刷、便携和柔性等优势。尽管BHJ太阳能电池性能缓慢提高：能量转换效率接近5%，但若大规模的商业应用需要进一步提高其性能。 Rather than using a single junction architecture, the fundamental BHJ concept involves the self-assembly of nanoscale heterojunctions by spontaneous phase separation of the donor (polymer) and the acceptor (fullerene). As a result of this spontaneous phase separation,charge-separating heterojunctions are formed throughout the bulk of