水热法制备纳米tio2 及其等电点的研究 - 高校化学工程学报.pdfVIP

19 1 No.1 Vol.19 2005 2 Journal of Chemical Engineering of Chinese Universities Feb. 2005 : 1003-9015(2005)01-0129-05 TiO2 , , , 樑 (, , 210009) 200 6 pH NaOH HCl pH 15~40nm pH Zeta XRD TEM pH pH 1,3,5,11,13 5.5pH 7 9 4.5 TQ134.11 O614.411 A Preparation of Nanometer Titanium Dioxide Powders by Hydrothermal Method and their Isoelectric Points QIU Yong-liang, CHEN Hong-ling, WANG Xiao-zu, XU Nan-ping (Key Laboratory of Material-Oriented Chemical Engineering of Jiangsu Province, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China) Abstract Through the hydrothermal process at 200 for 6h and using the metatitanic acid as reactant, the nanometer titanium dioxide powder were synthesized under different pH values adjusted by NaOH or HCl solution. The synthesized powders were characterized by Zeta potential, XRD and TEM. The TEM photographs show that the crystal structures are all anatase. The influence of pH on the isoelectric points of the synthesized titanium dioxide powders was studied and it shows that the pH conditions could influence the quantity of surface hydroxyl absorbed by the synthesized powders, thus influence the isoelectric points. Isoelectric points of the powders prepared in hydrothermal process with pH 1351113 are 5.5. and those in hydrothermal process with pH 79 are 4.5. When the hydrothermal reaction is processed in the acid solution then the acidness of the