荧光光度法测定纸中荧光增白剂VBL.pdfVIP

荧光光度法测定纸中荧光增白剂VBL 张少文，王万慧，孙雪萍，王永刚 (洛阳理工学院环境工程与化学系，洛阳471023) 摘要：采用荧光光度法测定纸中荧光增白剂VBL的含量。样品以pH8的水为解析液，微波 辅助萃取120S。VBL的质量浓度在2．00mg·L-1以内与其荧光强度呈线性关系，检出限(3s／k) 为0．001 mg·L～。以学生作业纸样品为基体进行加标回收试验，所得回收率在84．7％～94．9％ 之间。对同一纸品平行测定5次，测定值的相对标准偏差为3．4％。 关键词：荧光光度法；荧光增白剂ⅦL；纸 中图分类号：0657．3 文献标志码：A 文章编号：1001—4020(2015)02—0164—04 ofFluorescent Determination Fluorospectrophotometric VBLin WhiteningAgent Paper ZHANGShao-wen，WANGWan-hui，SUN Xue-ping，WANGYong-gang Environment and InstituteScience (Departmentof EngineeringChemistry，Luoyangof and 471023，China) Technology，Luoyang was tOthedeterminationoffluorescent VBLin Abstract：Fluorospectrophotometryapplied whiteningagent in wasdesorbedwaterof 8，thenextractedfor120Swithmicrowaveassistant．Linear paper．Thesample pH betweenvaluesoffluorescenceandmassconcentrationofVBLwas inthe within relationship intensity kept range 2．00 detection thebaseof of limit(3s／k)of0．001 worksheet student，test mg·L～，with mg·L～．On sample for was madestandardadditionmethod，withvaluesof foundinthe of84．7％--94．9％． recovery by recovery range Precisionofthemethodwastestedwith for5 ofRSDfoundwas papersampledetermination，value 3．4％． Keywords：Fluorospectrophotometry；Fluorescentwhiteningagent