脱氢枞酸蔗糖酯的无溶剂法合成研究论文.pdfVIP

全国第十三次工业表面活性剂研究与开发会议 脱氢枞酸蔗糖酯的无溶剂法合成研究 1 2 1 崔国友 , 莫炳荣 , 陈文纳 , 黄科润 1: 广西师范学院 化学系 南宁 530001; 2: 广西化工研究院 南宁 530001 摘要 首先从歧化松香中制得脱氢枞酸 用三种方法合成了脱氢枞酸甲酯 并对三种方法 进行了比较 最佳的方法是硫酸二甲酯与脱氢枞酸物质的量之比为 1:1 碳酸钾为催化剂 丙酮回流下进行 再以脱氢枞酸甲酯与蔗糖通过酯交换反应生成脱氢枞酸蔗糖酯 讨论了 反应物物质的量之比 反应温度 反应时间 催化剂的类型及用量和皂的用量对反应的影 o 响 确定了最佳的条件 温度 140 C 脱氢枞酸甲酯与蔗糖物质的量之比为 1:1.5 催化剂 碳酸钾的用量为 5% 皂用量为 10% 压强为 0.5KPa 反应时间为 5h 产率可达 32% 并 测定其表面张力和乳化能力 关键词 脱氢枞酸 脱氢枞酸蔗糖酯 合成 中图分类号 0621.3 文献标识码 文章编号 Synthesis of sucrose ester dehydroabietate by solventless method 1 2 1 2 CUI Guo-you , MO Bin-rong ,CHEN Wen-nan HUANG Ke-run (1:Department of Chemistry, Guangxi Normal College, Nanning ,530001; 2: Guangxi Research Institute Of Chemical Industry, Nanning ,530001,) Abstract : Dehydroabietic acid was isolated and purified from disproportionated rosin at first . Then, methyl dehydroabietate was synthesized with three methods and those methods also were compared. The best method was obtained as follows: the ratio of dehydroabietic acid to dimethyl sulfate was 1:1(mol/mol). The ratio of potassium carbonate to reaction material was 0.12:1(m/m), acetone was used as solvent. Sucrose ester dehydroabietate was synthesized by ester exchange method from methyl dehydroabietate and sucrose .Many factors including ratio of raw material, reaction temperature and time, amount of catalyst and soap were discussed. The optimum conditions were obtained as follows: the ratio of methyl dehydroabietate to sucrose was 1:1. 5(m