低游离TDI含量的聚氨酯预聚体制备研究.pdfVIP

2007 6 · 38 · 34 170 510641 TDI-TMP TDI TDI 0.5wt%TDI-TMP TDI-TMP MD-S80 140 400 Pa160 40Pa180 r/min100 12.0 g/min 75wt%TDI 0.50wt%-NCO 13.0±0.2wt% TDI-TMP TDI Study on the Manufacture of Polyurethane Prepolymer with Low Content of TDI Chen Xiaorui, Huang Hong, Yin Daiwu, Hu Xiaoyong, Chen Huanqin (Department of Chemical Engineering, South China University of Technology, Guangzhou 510641, China) Abstract: This paper summarized the major factors which affected the process of double-stage separating TDI from polyurethane prepolymer by thin film evaporator and the optimum conditions under which proceeding separation procedure. The better optimized operation conditions were obtained to get the low TDI contamination in TDI-TMP prepolymer, which was less than 0.5wt%. The optimum conditions of TDI-TMP preolymer separation in MD-S80 thin film evaporator were as following: temperatures of first-stage evaporation and second-stage were 140 and 160 , pressure were 400 Pa and 40 Pa, rotate speed of scraping plank was 180 r/min, feeding speed was 12.0 g/min, with temperature 100 . At last the product of polyurethane prepolymer was obtained with perfect quality, the remaining free TDI was less than 0.5 wt%, solid content and –NCO content of prepolymer were 75 wt% and 13±0.2 wt% respectively. Keywords: thin film evaporator TDITMP prepolymer TDI separation PU TDI-TMP TDItoluene diisocyanate 2,4-TDI 2,6-TDI TMP(trimethylol propane) TDI-TMP (1) CASE coa