高铝陶瓷显微结构及制备工艺对金属化层性能影响的研究.pdfVIP

第36卷 第6期 人 工 晶 体 学 报 Vo1．36 No．6 2007年 l2月 JOURNAL OF SYNTHETIC CRYsTALS December，2007 高铝陶瓷显微结构及制备工艺对 金属化层性能影响的研究 石 棋 ，郭志猛 ，郝俊杰 ，罗凌虹 (1．北京科技大学，北京100083；2．景德镇陶瓷学院，景德镇333001) 摘要：通过配方及烧成工艺的改变，得到两种不同显微结构的高铝陶瓷材料，其一为晶粒大小均匀，边界清晰，晶粒 堆砌结构；其二为晶粒大小不一，晶粒边界不清，甚至晶粒被包裹在玻璃相中，形成玻璃相堆积结构。测定了材料 的抗折强度、体积电阻率、抗击穿强度、比重、金属化层抗张强度和气密性。分析了两种显微结构的成因及不同微 观结构对陶瓷材料性能和金属化层性能的影响。实验证明：采用微粉氧化铝配料，利于获得金属化性能优良的细 晶结构的高铝陶瓷材料；用粗粉氧化铝配料，并加入复合的添加剂，也可以获得细小晶粒堆砌结构的高铝陶瓷材 料，这类结构高铝陶瓷材料的金属化层性能好。 关键词：高铝陶瓷；显微结构；金属化 中图分类号：TQI74 文献标识码：A 文章编号：1000-985X(2007)06-1382-04 Effect of High Alumina Ceramic Microstructure and Preparation on Performance of Metal-cerami c Layer SH／Qi ，GUO Zhi．meng ，HAO Jun-jie。，LUO Ling—hong (1．University of Science and Technology Beijing，Beijing 100083，China；2．Jingdezhen Ceramic Institute，Jingdezhen 333001，China) (Received 2 Feburary 2007) Abstract：In the present paper，two kinds of high alumina ceramic materials with different structures were obtained through the change of formula and sintering schemes．The microstructure of one sample showed the crystalline grains were uniform in size and the body was piled up by the crystalline grains．The microstructure of another one showed the crystalline grains were different in size，and the grains were surrounded by the glass phase，which formed the glass stacking structure．Some properties of the sintered samples such as fracture strength，volume resistivity，bulk density，tensile strength and helium leak density were measured．The results indicated that using fine alumina powder in formula was beneficial to obtaining high alumina ceramic materials with exc