有机胺对CO 2 吸收解吸的研究.PDF

中国环境科学 2011,31(7) ：1109~1114 China Environmental Science 有机胺对 CO2 吸收解吸的研究 * 陈春宜,王祖武 ,魏文龙,程 诚,王骏星,周家勇,车 垚 (武汉大学资源与环境科学学院,湖北 武汉 430079) 摘要：利用常压搅拌吸收-解吸装置,在不同温度和浓度条件下,对 MEA( 乙醇胺) 、DEA(二乙醇胺) 、MDEA(N-甲基二乙醇胺) 、TETA( 乙烯四胺) 、DETA(二乙烯三胺)5 种有机胺吸收解吸 CO 进行研究.探讨了反应温度、吸收液浓度、有机胺种类对 CO 吸收和解吸过程的 2 2 影响规律,并利用正交试验法筛选出性能较好的混合胺复配剂.结果表明,当 TETA/DEA=5:1,吸收温度为 318K,解吸温度为 388K 时,混合胺 具有较优的吸收解吸综合性能. 关键词：CO ；有机胺；吸收；解吸；混合胺 2 中图分类号：X131.1 文献标识码：A 文章编号：1000-6923(2011)07-1109-06 Research of carbon dioxide absorption and desorption in organic amine aqueous solutions. CHEN Chun-yi, WANG * Zu-wu , WEI Wen-long, CHENG Cheng, WANG Jun-xing, ZHOU Jia-yong, CHE Yao(Resources and Environment Science School, Wuhan University, Wuhan 430079, China). China Environmental Science, 2011,31(7)：1109~1114 Abstract ：The absorption and desorption process of CO2 in different organic amine aqueous solution (MEA, DEA, MDEA, TETA, DETA) were compared and analysed in a stirred reactor under normal pressure. The effect of reaction temperature and amine concentration on the absorption and the desorption process in each amine solution was studied. At the same time, the absorption and desorption of CO2 in mixed organic amine is also investigated by orthogonal experiment and an optimized program is obtained. It was found that the comprehensive performance of absorption and desorption of mixed organic amine with molar ratio of TETA and DEA as 5:1 is better under the conditions of an absorbing temperature at 318K and a desorbing temperature at 388K respectively. Key words ：CO2 ；organic amine ；absorption ；desorption ；mixed amines CO2 气体是导致全球变暖气候变化最主要