PANI_MATMS杂化透明导电薄膜的表征_栾晶.pdfVIP

DOI :10.14135/j.cnki.1006 -3080.2012.01.003 ( ) Vol.38 No.1 34 　　　　　　Journal of East China University of Science and Technology (Natural Science Edition) 2012-02 　　:1006-3080(2012)01-0034-05 PANI-MATMS 栾　晶, 　王庚超, 　陈　奇 (华东理工大学材料科学与工程学院,超细材料制备与应用教育部 重点实验 , 上海市先进聚合物材料重点实验 , 上海200237) 　　:以聚苯胺(PANI)和γ-(甲基丙烯酰氧)丙基三甲氧基硅烷(MATMS )为反应物,采用溶 胶-凝胶法制备了杂化透明导电薄膜。由红外光谱和X 射线光电子能谱的结果可知:PANI 和 MATMS 形成杂化结构。TG-DTA 分析表明:PANI-MATMS 杂化薄膜的热稳定性比PANI 好。 研究了不同的PANI 质量分数对薄膜透过率和方块电阻的影响。随着PANI 质量分数的增加, 薄 膜的可见光透过率逐渐下降, 方块电阻也降低。当PANI 质量分数为30%时, 所得到的杂化薄膜 的综合性能较佳, 可见光透过率可达87%,薄膜的方块电阻为4.36 kΨ/◆。 :溶胶-凝胶;透明导电薄膜;聚苯胺;有机-无机杂化 :O613.72;O63 :A Characterization of PANI-MATMS Transparent Conducting Hybrid Films L UA N J ing , 　WAN G Geng -chao, 　CHE N Qi (K ey L aboratory f or Ultraf ine Materials of Ministry of Education , S hanghai K ey L aboratory of Ad anced Poly meric Materials, S chool of Materials Science and Engineering , East China Uni ersity of Science and Technology , S hanghai 200237, China) Abstract:T ransparent conducting hybrid films were synthesized via a sol-gel route, using polyaniline (PANI)and hydrolytic polycondensed by [3-(methacryloyloxy )propyl] trimethoxysilane (MATMS )as precursors.The results of infrared spectra and XPS spectrum indicated that the hybrid network between PANI and silane coupling agent was formed.The analysis of TG-DTA curves showed that the thermal stability of PANI-MATMS was better than that of pure PANI.Moreover, the effect of mass fractions of PANI on the transparence and sheet resistance of hybrid f