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Sensors and Actuators B 199 (2014) 108–114 Contents lists available at ScienceDirect Sensors and Actuators B: Chemical j o u r n a l h o m ep a g e: w w w. elsev /locate/snb Detection of trace mercury ions in water by a novel Raman probe Shuyue Fu, Xiaoyu Guo, Hui Wang, Tianxi Yang, Ying Wen, Haifeng Yang ∗ The Education Ministry Key Lab of Resource Chemistry, Shanghai Key Laboratory of Rare Earth Functional Materials and Department of Chemistry, Shanghai Normal University, Shanghai 200234, PR China a r t i c l e i n f o a b s t r a c t Article history: The convenient chemical method for sensing mercury ion (Hg2+ ) has drawn significant attention in recent Received 3 February 2014 researches. Herein we report a simple, ultrasensitive and inexpensive protocol to detect trace mercury Received in revised form 18 March 2014 ions in water without complicatedly tagging, based on the facile synthesis of a nanocomposition, which is Accepted 21 March 2014 constructed with inositol hexaphosphate (IP6 ) stabilized gold nanoparticles (Au NPs) modified by crystal Available online 1 April 2014 violet (CV) as Raman signal molecule and tri-sodium citrate (TC) as reducer, shortly named CV/TC/IP /Au 6 NPs. A possible mechanism for the Raman probe is the decreasing intensity of SERS band at 1173 cm−1 of Keywords: