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计算机在化工中的应用-习题集(The application of computer in Chemical Engineering)
计算机在化工中的应用-习题集(The application of computer in Chemical Engineering)
The jingle bells MT contribution
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Application of Matlab in Chemical Engineering
Chapter 1 numerical analysis and solution in Chemical Engineering
1.1. simple distillation calculation (fzero), the relation between the liquid residue F and the boiling point x at a certain time in a simple distillation process is:
LN, F0 1, x0 1, x, LN, LN, F, 1, x, 1, x0?
For benzene toluene series, the relative volatility is a=2.5, and at the beginning the benzene content is 60%. The benzene content in the residual liquid when the amount of distillation to the residual liquid is half of the original feed amount. 1.2. equation of state for gases (fzero or roots)
The form of the 2 Van de Waals equation is: P, an2, V, Nb, nRT,?
V?
At 945.36kPa, 300.2K, a vessel is filled with 2mol nitrogen, and the volume of the gas is calculated according to the Van de Waals equation of state. The known Van, De, and Waals constants are:
A? 4.17 ATM? L2 / mol2 B? 0.0371 L/mol
Thinking: Van, De, Waals equations should have three roots, and what are the physical meanings of the three roots? Bubble and balance calculation steam 1.3. mixed liquid composition (fzero) calculation of 101.325kPa benzene 50% (molar fraction, the same below), and the bubble equilibrium vapor mixture of toluene and ethylbenzene 30% 20%. The relation between the saturated vapor pressure and the absolute temperature for each pure component I is known to satisfy the Antoine equation: LG
Pi0, B, AI, I, mmHg, T, /K
Coefficients a and B are listed in the following table: I, 123 components, benzene, toluene, ethylbenzene, AI 7.84135, 8.08840, 8.11404, Bi 175019852129
1.4. calculation of isothermal flash (fzero) as shown in the figure, the feed composition as shown in the following table four component alkane mixtures in 13
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