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Polish Journal of Environmental Studies Vol. 8, No. 1 (1999), 35-38
Spectrophotometric Determination of Copper(II) in
Samples of Soil from Selected Allotment
Gardens in Lodz
B. Jankiewicz, B. Ptaszyński, A. Turek
Institute of General and Ecological Chemistry, Politechnical University, Lodz, Poland
Received 26 June, 1998
Accepted 15 October, 1998
Abstract
The content of copper in the soil of two allotment gardens in Lodz and a forest area near Lodz were
determined. Copper was determined by an adapted extraction - spectrophotometric method in the form of
a complex with sodium(I) diethyldithiocarbamate. The influence of the extraction solvent, a masking agent and
interfering elements (Fe(III) and Cr(IH)) on determination of copper by this method was examined. Possibilities of
elimination of the extraction stage by using a protective colloid for spectrophotometric determination of copper in
soil were investigated.
Keywords: copper(II), diethylodithiocarbamate, soil
Introduction centration is 8.8 mg per kg of soil. In polluted soils the value
is 50 mg per kg and in contaminated soils it is over 200 mg
Soil plays an important role in biogeochemical balance per kg of soil. According to the guidelines of the Institute of
of the biosphere. Degradatio
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