包含聚苯胺的相变材料纳胶囊的制备及其性能 南光花.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) 338 Acta Phys. -Chim. Sin. 2014, 30 (2), 338-344 February [Article] doi: 10.3866/PKU.WHXB201312231 包含聚苯胺的相变材料纳胶囊的制备及其性能 南光花 王建平* 王 艳 王 赫 李 伟 张兴祥 (天津工业大学功能纤维研究所, 改性与功能纤维天津市重点实验室, 天津300387) 摘要: 采用自由基乳液聚合法和原位聚合法制备了包含聚苯胺均匀分散在正十八烷中的悬浮体系的交联聚 甲基丙烯酸甲酯为囊壁的相变材料纳胶囊(NanoPCMs). 采用扫描电子显微镜(SEM)、差示扫描量热仪(DSC)、 热重分析仪(TG)和广角X 射线衍射仪(WAXD)等手段分别考察了成核剂聚苯胺的添加量对相变材料纳胶囊表 面形态、结晶性能、热稳定性及结晶行为等的影响. 实验结果表明: 包含有聚苯胺的相变材料纳胶囊, 成核剂的 存在对其形貌、粒径、包覆率和结晶行为影响较小, 耐热性略有所降低, 添加1.5 g 苯胺时生成的成核剂聚苯胺 可以有效改善其过冷结晶行为. 关键词: 相变材料纳胶囊; 正十八烷; 交联聚甲基丙烯酸甲酯; 聚苯胺; 过冷 中图分类号: O648; O642 Preparation and Properties of Nanoencapsulated Phase Change Materials Containing Polyaniline NAN Guang-Hua WANG Jian-Ping* WANG Yan WANG He LI Wei ZHANG Xing-Xiang (Tianjin Municipal Key Laboratory of Fiber Modification and Functional Fibers, Institute of Functional Fibers, Tianjin Polytechnic University, Tianjin 300387, P. R. China) Abstract: Nanocapsules containing polyaniline homodispersed in n-octadecane (n-Oct) were synthesized by free radical emulsion polymerization and in situ polymerization using poly(methyl methacrylate- co-allyl methacrylate) (P(MMA-co-AMA)) as a shell, in which polyaniline was used as the nucleating agent. Furthermore, the surface morphologies, crystallization properties, thermal stabilities, and crystallization process of nanoencapsulated phase change materials (NanoPCMs) were investigated using scanning electron microscopy