多孔ZrO2-HA涂层复合材料的制备工艺.pdfVIP

第 26 卷第1 期 材料科学与工程学报 总第 111 期 Vo l. 26 No. 1 Journal of Materìals Scìence . Engìneering Feb.2008 文章编号:1673-2812(2008)01-0098-03 多孔 Zr0 -HA 涂层复合材料的制备工艺 2 王莉丽，王秀峰 {陕西科技大学材料科学与工程学院，陕西西安 710021) E摘 要】 采用凝胶成型法制备多孔氧化错CZrO， )支架，通过改变循环次数实现了对孔隙率的可控，使其保 持在 91%~45%之间，并且每循环一次，孔隙率稳定下降 4~5% 。在多孔 ZrO，的表面涂覆短基磷灰石CHM涂 层。为了防止 HA 和 ZrO，之间的化学反应，中间涂覆了氟磷灰石CFM 层。 XRD 表明加了 FA 层作为中间层以 后，没有发现反应发生。体视显微照片表明在 HAlFA 和 FA!ZrO，两个界面上没有出现分层和裂纹，层与层之间 结合紧密。 E关键词】 多孔氧化错;控基磷灰石g 孔隙率可控;涂层 文献标i只码:A 中图分类号:R318.08 Preparation of Porous zr0 Bone Scaffold Coated with Hydroxyapatite 2 WANG L i-li , WANG Xiu-feng CSchool of Material Science and Engin优ring ， Shaanxi Unìverstìy of Scìence and Technology , Xian 710021 , China) (Abstract A novel technique that integrates the gel-casting technique with polymer sponge method to prepare ZrO , porous scaffolds with controllable porosity C91 % ~45 %) was reported. The pore morphology , size , and distribution of the scaffolds were characterized using an electron microscope. Porous ZrO , was chosen as a framework for load-bearing and the HA was used as an outer coating layer to enhance the biocompatibility. To prevent the chemical reactions between Zr02 and HA , an intermediate fluorapatite CFA) layer was introduced. The coated HA/FA layer was firmly adhered to the ZrO , body. (Key words porous ZrO ,; hydroxyapatite; controllable porosity; coating 相结合，各取其长.是当今国内外研究的热点.已有一些进 -主­ 展。如 Yun-Mo Sung[5] 用化学沉淀法制备出了 ZrO，和 HA