DMA资料.ppt

* * * * Tg and the drop in modulus are also nearly independent of MW if the MW is high enough for applications where mechanical strength becomes important With the exception of low molecular weight (below Mc where there are no entanglements), the rubbery plateau region above Tg is strongly dependent on MW. In the absence of true crosslinks, the behavior is determined by entanglements. The length of the rubbery plateau is a function of the number of entanglements per molecule. * * * * * * Each of the 4 main zones in the polystyrene data is illustrated with a creep test done at the appropriate. temp it is clear to see changes in shape of creep curves as response goes from elastic [square wave, fullrecovery] to v/e [curved, 75% recovery], to rubbery flow [almost a liquid response but some recovery] to liquid flow [even some acceleration in the retard. section, no recovery] * headings are dealt with in furtherdepth in subsequent slides bullet points reflect key concerns in DMA * read slide * It is important to emphasize that the force range of the DMA corresponds to a range of stiffness acceptable in any given clamp configuration Stiffness is an extrinsic property and depends on the samples dimensions [length and thickness nnormally] Modulus is an intrinsic property of a material e.g. the modulus of Steel = X GPa. This value will not change at a given Temp. To measure the modulus of steel a thin enough piece must be used [correct Stiffness] * modulus calculation: geometry factor is extracted from equation so all instrument components are lumped together controller + software handle calculations * details of geometry factors * clamping hints * elastomer hints * coatings and resins = DMA of liquids or cured films [solids] * reference table * read the slide: this year the single cantilever set up is recommended over the dual for most thermoplastics [expansion] * * * * * 线性高分子可以被视为一维协同体系，在这个体系中链段的旋转被邻近的链段限制或协助。 在无定形状态下，高分子链在阵列中的贡献是完全随机的。没有任何结构被有序结构影响，像半结晶高分子中的结晶。这就允许无