辐射接枝甲基丙烯酰胺对蚕丝织物服用性能的影响.PDFVIP

安徽农业大学学报, 2012, 39(6): 1008-1012 Journal of Anhui Agricultural University 网络出版时间：2012-10-26 14:05:41 [URL] /kcms/detail/34.1162.S1405.003.html 辐射接枝甲基丙烯酰胺对蚕丝织物服用性能的影响 刘 陶，许云辉，胡凤霞，黄 晨，戴小丽，鲍小倩 (安徽农业大学轻纺工程与艺术学院，合肥 230036) 摘 要：以甲基丙烯酰胺为单体，在钴 60 辐射条件下对蚕丝织物进行接枝改性，并对改性后的织物各项性能 指标进行测试，分析测试结果，探索辐照剂量、单体质量分数、溶液 pH 值等对接枝率及织物各项性能的影响。结 果表明，接枝改性后，织物干缓弹性回复角增大，织物的抗皱性能获得较大的改善，织物的吸湿性变化不大，断裂 强力和白度有所下降。通过 3 因素 4 水平的正交试验综合考虑得出最佳的处理工艺为：单体质量分数 20% ，溶液 pH 值 4 ，辐照剂量40 kGy 。并采用红外光谱法对接枝后的蚕丝织物进行了表征。 关键词：蚕丝织物；钴 60 辐射；甲基丙烯酰胺；接枝 中图分类号：TS195.6 文献标识码：A 文章编号：1672−352X (2012)06−1008−05 Effects of radiation-induced graft copolymerization of methacrylamide on properties of silk fabric LIU Tao, XU Yun-hui, HU Feng-xia, HUANG Chen, DAI Xiao-li, BAO Xiao-qian (School of Light-Textile Engineering and Art, Anhui Agricultural University, Hefei 230036) Abstract: In this paper, we studied graft copolymerization of methacrylamide monomer onto the silk fabrics 60 by radiation of Co γ-ray and investigated the influence of radiation dose, monomer mass fraction and pH value of the treatment solution on the graft yield ．Properties of the grafted fabric were tested and the results indicated that after graft modification, the silk fabric exhibited significant improvement in delayed elastic recovery and crease resistance, little change in moisture absorption, and slight fall in breaking strength and whiteness. The op- timal graft rate treatment process conditions were determined by orthogonal experiments through observing the delayed elastic recovery angles ：monomer mass fraction, 20 ％；pH value, 4; radiation dose, 40 kGy. Furthermore, the radiation grafted silk with methacrylamide was characterized by the infrared spectrum.