菟丝子中两个中性杂多糖的化学结构研究.PDFVIP

　Chinese Traditional and Herbal Drugs　2001 32 8 ·6 5· 王　展,鲍幸峰,方积年 ( , 　200031) 　: 　 Cuscu ta ch inens is Lam. 。　 DEAE-cellulose ,,。　 5 2 , H6 H8, H6 3. 14× 10 u, H8 1. 0× 6 10 u,, ,,。　 。 : ;; NMR; : R284. 1　　　: A　　　: 0253 26 0(2001) 08 06 5 04 Studies on structural features of two neutral heteropolysaccharides from Cuscuta chinensis W ANG Zhan, BAO Xing-feng, FANG Ji-nian 　　( Shanghai Institute of Materia Medica, Shanghai Institute of Life Sciences, Chinese Academ y of Sciences, Shanghai 200031, China) Abstract: Object　Polysaccharide constituents in the seed of Cuscuta ch inensis Lam. . w ere investigat- ed. Methods　Individual constituent w as isolated and purified by DEAE-cellulose and gel-filtration chro- matography , and its structural features w ere further studied by physicochemical constants, and spectral analysis. Results　Tw o polysaccharides, named H6 and H8, w ere obtained from alkalescent or boiling w a- 5 ter extract fractions, respectively. The molecular mass of H6 w as 3. 14× 10 and that of H8 was more than 6 1. 0× 10 . Both structures w ere found to be complex neutral heteropolysaccharides composed of Ara, Rha, Gal and Xyl. Conclusion　These polysaccharides w ere obtained from this plant for the first time. Key words: Cuscu ta ch inensis Lam. ; neutral heteropolysaccharides; NM R spectrum; methylation analysis 　　 Cuscu ta ch inensis Lam. , ,,,, M erck 。 。 ,,, , T Dextran, Pharmacia。 [1] [2, 3] ( 4 ) , ( ) 。 。 , NaBH TFA Merck ,。