煤的高位发热量与低位发热量有什么区别（What is the difference between the high calorific value of coal and the low calorific value）.docVIP

煤的高位发热量与低位发热量有什么区别（What is the difference between the high calorific value of coal and the low calorific value） What is the difference between the high calorific value of coal and the low calorific value? The name of the calorific value of coal A. the heat of the shell of the coal (Qb) The heat generated by the shell of a coal is a sample of a unit mass of coal. The heat produced by burning in excess of the high pressure oxygen (about 25~35 atmospheres) in the bomb barrel of the calorimeter (the final temperature of the product is set at 25C). Because coal samples are burned in a high-pressure oxygen bomb, a thermochemical reaction that occurs when coal is fired in the air is avoided. For example, the nitrogen in the coal and the nitrogen in the air in the front shell of the oxygen tank are usually gaseous nitrogen when they are burned in the air, while the N2O5 and NO2 nitrogen oxides are generated when the bomb is burned. These nitrogen compounds are dissolved in the shell of the bomb to produce nitric acid, which is exothermic. In addition, when the combustible sulfur in coal burns in the air, the SO2 gas escapes, while in the cartridge, it is oxidized to SO3 when it is burned, and SO3 is dissolved in the shell water to produce sulfuric acid. SO2, SO3, H2SO4 and soluble sulfate hydrate in water is exothermic reaction. Therefore, the heat of the shell of the coal bomb is higher than that of coal, and combustion in the air and industrial boilers is the actual heat generated. To this end, the actual heat of the cartridge will be converted into coal in accordance with the burning of heat in the air. High calorific value of B. coal (Qgr) The high calorific value of coal, that is, the heat produced by burning coal under atmospheric pressure in the atmosphere. In fact, the heat produced by the shells of the coal measured in the laboratory minus the heat generated by sulfuric acid and nitric acid. It should be pointed out that the calorific value of the shell of a coal b