MAl2O4 Eu2+ 、RE3+ 长余辉发光性质的研究 - 发光学报.PDF

20 2 Vol . 2 0 , No . 2 199 96 CHINESEJOU RNALOFLUM INESCENCE June, 1999 2+ 3+ M Al O Eu 、RE 长余辉发光性质的研究 2 4 张天之　苏　锵　王淑彬 ( , , 130022) 2+ 3+ ( = , , , ; = , M Al2O4 Eu RE M Mg Ca Sr Ba RE Y La, Ce, Pr, Nd, S , Gd, Tb, Dy, Ho, Er, T , Yb, Lu) . 2+ 3+ 3+ Eu 4f- 5d . RE , . RE 2+ 3+ 3+ , . , , M Al2O4 Eu RE RE X-, , , . , , , , 1　引　　言 [ 1] 2+ 1968, 2 4 2 4 Palilla SrAl O Eu SrAl O 2+ 2+ e 2 4 Eu ( = 520n ) . SrAl O Eu : , 10sec; , . , 3 147 H, P ZnS Cu, Co, [2] 2+ 3+ . , Eu , Dy 3+ 2+ [26] 2 4 2 4 SrAl O , Dy SrAl O Eu , [8] 2000 in . 2+ 3+ 2 4 M Al O Eu RE (M = Mg, Ca, Sr, Ba; RE= Y, La, Ce, Pr, Nd, S , Gd Tb Dy Ho Er T, , , , , , Yb Lu, ), , , , . 2　实验部分 2+ 3+ 2. 1M Al2O4 Eu , RE SrCO3, (MgCO3)4Mg(OH) 25H2O, CaCO3, BaCO3, -Al2O3, (P )(99.9%99.999%) , 1%5%B2O3 , , 1200 5. X- , 2 4 , 2 4 , 2 4, 2 4 . MgAl O C