Co2+含量对钴铁氧体薄膜结构及磁性的影响 Influence of Co2+ Content on the Microstructure and Magnetic Properties of Cobalt Ferrite Films.pdfVIP

研究·分析·实验 Co2+含量对钴铁氧体薄膜结构及磁性的影响 李 雁，方庆清，吕庆荣，刘艳美，尹 平，陈 辉 （安徽大学物理与材料科学学院 安徽省信息材料与器件重点实验室 教育部 光电信息获取与控制重点实验室，安徽合肥 230039 ） 摘 要：采用溶胶-凝胶法在玻璃衬底上制备了钴铁氧体 Co Fe ― O ( x = 0.2~0.8)薄膜。分别用振动样品磁强 x 3 x 4 计及 X 射线衍射仪对样品的磁性和结构进行了测量与分析。结果表明，随 Co2+含量增加，样品中的尖晶石相衍 射峰逐渐增强，至 x=0.8 时为单一的尖晶石结构。高 Co2+含量（x ＞0.7 ）样品的饱和磁化强度和矫顽力随退火温 度的升高呈上升趋势，630 ℃退火Co0.8Fe2.2O4 薄膜矫顽力达 156kA/m。Co2+含量的增加还可使晶粒细化。当 Co2+ 含量 x=0.8 时，可同时获得好的磁性能及小的晶粒。 关键词：钴铁氧体薄膜；溶胶-凝胶法；晶粒细化；磁性；结构 中图分类号：TM277+ + .1; O484.4 3 文献标识码：A 文章编号：1001-3830(2006)06-0030-04 2+ Influence of Co Content on the Microstructure and Magnetic Properties of Cobalt Ferrite Films LI Yan, FANG Qing-qing, LV Qing-rong, LIU Yan-mei, YIN Ping, CHEN Hui Department of Physics, Anhui University, Anhui Key Laboratory of Information Materials and Devices, Key Laboratory of Opto-Electronic Information Acquisition and Manipulation of the Ministry of Education, Hefei 230039, China Abstract: Co Fe － O (x = 0.2-0.8) ferrite films were synthesized on glass substrates by sol-gel technique. The x 3 x 4 magnetic properties and microstructure were measured and analyzed by vibrating sample magnetometer and X-ray diffraction. The results reveals that the peaks of spinel phase becomes higher gradually with increasing amount of Co2+ ions, and then single spinel phase is formed at x= 0.8. The saturation magnetization and the coercivity of samples with x ＞0.7 increase with increasing annealing temperature. The Co0.8Fe2.2O4 films annealed at 630