有机功能性无机复合材料资料.docVIP

研读报告/文献综述 1、有机/功能性无机复合材料界面改性及性能特点研究 Interface characterization and preparation of organic——inorganic composites 2、有机一无机复合材料的制备与界面特性 3、（无机粒子填充型ZnO、Al） 4、高导热先进复合材料设计制备、应用研究 5、无机粒子改性聚丙烯材料聚丙烯基导热复合材料的配方设计填充型聚合物基导热材料的研究和应用南京工业大学聚合物基导热材料的研究选用聚丙烯(PP)和聚四氟乙烯(PTFE)为基材,高导热性能的石墨、铝粉和铜粉作为导热填料进行改性。 四针状氧化锌晶须／PP导热绝缘复合材料的制备与性能研究 並列篇名 Study on the Preparation and Properties of Thermally Conductive and electric-insulating T-ZnOw/PP Composites 作　者 李光吉(Guang-Ji Li);冯晖(Hui Feng);童奇勇(Qi-Yong Tong) 刊　名 材料研究與應用 卷期／出版年月 2卷4期(2008/12) 頁次 511-516 以聚丙烯(PP)为基体，四针状氧化锌晶须(T-ZnO(下标 w))为导热填料，用双螺杆挤出机制备导热绝缘的T-ZnO(下标 w)/PP复合材料。在w(T-ZnO(下标 w))为0~30%的范围内，探讨了T-ZnO(下标 w)的用量对T-ZnO(下标 w)/PP复合材料的热导率(λ)、体积电阻率(ρ(下标 v))、力学性能和加工性能的影响。结果表明，随T-ZnO(下标 w)用量的增加，T-ZnO(下标 w)/PP复合材料的热导率提高，体积电阻率下降；材料的拉伸强度、弯曲强度以及冲击强度均随T-ZnO(下标 w)用量的增加呈先增大后减小的趋势，而熔体流动速率则呈增大趋势。当T-ZnO(下标 w)用量达30%时，材料的热导率达到最大值0.3803 W?(m?K)^(-1)，比纯PP提高了55.9%；体积电阻率达到最小值6.17×1016Ω?cm，比纯PP降低了64.5%，仍可满足绝缘材料的要求。对其断面结构的观察表明，T-ZnO(下标 w)的针状结构有利于在PP基体中形成导热通路，从而提高材料的热导率。Thermally conductive and electric-insulating polypropylene (PP) composites were prepared with a twin-screw extruder using tetrapod zinc oxide whisker (T-ZnO(subscript w)) as thermal conductive filler. The effects of T-ZnO(subscript w) content on the thermal conductivity (λ), volume resistivity (ρv), mechanical properties and processability of the T-ZnO(subscript w)/PP composites were investigated within the range of T-ZnO(subscript w) content from 0 to 30%. The results indicate that as the content of T-ZnO(subscript w) increases, the thermal conductivity of the T-ZnO(subscript w)/PP composites increases while the volume resistivity decrease; besides, the tensile, flexural and impact strength of the T-ZnO(subscript w)/PP composites exhibit a tendency to increase firstly and then decrease, and the melt flow rate exhibit a tendency to increase. The T-ZnO(subscript w)/PP composite filled with 30% of T-ZnO(subscript w) possesses the maximum thermal conductivity and the minimum volume resistivity. The form