煤焦油蒸馏残留物制备燃料油的性能研究.docVIP

本科毕业论文 题目： 煤焦油蒸馏残留物制备燃料油的性能研究 学 院: 化学工程与技术 专 业: 化学工程与工艺 学 号: 200922146014 学生姓名: 曾伟 指导教师: 梁文懂 日 期: 二〇一三年六月  摘 要 煤焦油沥青乳化制备燃料油，拓展煤焦油沥青综合利用的途径为煤沥青深加工的工艺选择提供依据。在分析煤沥青软化点指标的基础上，羟基乙叉二膦酸（HEDP）作为稳定剂和乳化剂，考查的适宜加入比例、掺水比例、乳化温度以及搅拌转速等条件对煤焦油沥青乳化液的稳定性、流动性的影响试验结果表明HEDP在乳化可使乳液黏度减小，加入量在0.2%之间，0.2%，煤沥青的加入量对影响得到的最佳制备条件为 关键词：煤沥青； HEDP；乳化； Abstract Emulsion preparation of fuel oil from coal tar pitch can expand the approaches of comprehensive utilization of coal tar pitch and provide the basis for coal tar pitch deep processing technology choice. This study based on the analysis of the coal tar pitch softening point index, selects the hydroxy ethidene phosphonic acid (HEDP) as a stabilizer and emulsifier, examines the suitable adding ratio of HEDP, water blending ratio, emulsifying temperature and stirring speed and other conditions’ influence on the stability and liquidity of the emulsion. And the emulsification mechanism has carried on the preliminary analysis. Experimental results show that HEDP in the process of emulsification, act as the emulsifier and the stabilizer at the same time, can reduce the viscosity of the emulsion and maintain a stable state. Suitable adding level of HEDP was between 0.1 ~ 0.2%, when it is more than 0.2%, there was an increase in costs on the contrary, the liquidity and stability of the emulsion has no obvious improvement; The dosage of the added coal tar pitch has significant effects on the liquidity, and there exists a suitable dosage; The addition of water will form water-in-oil structure, which can lower the viscosity of emulsion, and improve its stability; A suitable dosage of doping anthracene oil can reduce the emulsifying time and improve the stable performance; After the single factor experiment, the optimum preparation conditions is found. That is water addition amount of 15%, HEDP addition amount of 0.14%, and 5% for the amount of coal tar pitch, the preparation of the emulsion stability and liquidity are better. Key wor