泡沫铜的制备及其在锂离子蓄电池中的应用 preparation of copper foam and its application in lithium ion battery.pdfVIP

泡沫铜的制备及其在锂离子蓄电池中的应用 张成1，张世超，，蒋涛：，五汉中1，于金花1 (1．北京航空航天大学材料辩学与工程学院，北京100083；2．清华大学化学系，北京100084) 摘要：通过塑料电沉积法制备出平均孔隙率为97％的泡沫铜。使用调节电流密度、热处理气氛及热处理温度等方法。改 善了泡沫铜的性能。泡沫铜的力学测试缡果显示了较好豹机械性能。将机械球磨法制得的硅粉与碳黑以及粘合荆 {PVDF；调割或浆瓣，然嚣填入泡濠铜审潮备出受极冀。将魏极楚缀装或钮翔毫港进纡缀嚣伏安以及充放毫测试，结 果表明泡沫铜的篓维结构可有效抑制硅的体积变化。掇高其电化学性能。 关键词：泡沫铜；键离子蓄电池；负极；硅 审鍪分类号：TM912。9 文藏标识鹌：A 文章编鼍：1002一087 X(2008)01—0017-04 of foamits in and lithiumion Preparationcopper application battery ZHANG Shi—cha04，JIANGTa02，WANG Jin-hual Chen91，ZHANG Han—zhon95，YU ofMaterialsScienceand ofAeronauticsand ff．School Engineenng,BeijingUniversity Astronautics,Beijing 1 ofChemistry,Tsinghua00084，China) University,Be(ring foamwith was current andthe method，the Abstract：Copperhighporositypreparedbyelectro-deposition density environmentand ofheattreatmentwerecontrolledtoachieve mechanical temperature improved silicon mechanical wasmixedwith andPVDF。The resultedwas powderpreparedby millingprocess graphite slurry thenfilledinto toworkas of the foam anode。Theresults and te蛱 copper cyclicvoltammetrycharge—discharge demonstratethatthethree-dimensionalstructureof foamcan restrainsilicon’Svolume and copper effectively