4习题 第四章化学平衡（4 exercises, fourth chapters, chemical balance）.doc

4习题 第四章化学平衡（4 exercises, fourth chapters, chemical balance） Exercise fourth chapter chemical balance Radio examination 1, at constant temperature and constant pressure, a chemical reaction is going on spontaneously. It must be () A. rGm 0 rGm0 C.? B. Delta Delta rGm0 D. (G/ T, p0.) 2, the reaction of CO (g), +H2O (g), =CO2 (g), +H2 (g) at 800 degrees K, =1, if the reaction begins at CO and H2O concentrations are 1mol = dm-3, then CO at 800 degrees of temperature conversion rate is () A.0.5 B.0.1 C.1 D.0.3 3, when the sum of the chemical potential of the product is equal to the sum of the chemical potential of the reactant, it must be () A. rGm (E) 0 B. (G/ T p0 C. (E), G/ T, p0 D. (E) G/. T, p=0) 4, at constant temperature and constant pressure, when a chemical reaction reaches a balance, the relationship must be established A., rGm0, B.,, rGm0, C., Delta, rGm=0, D., Delta, rGm, 0 5, when the sum of the chemical potential of the product is less than the sum of the chemical potential of the reactants, it must be () A. rGm (E) 0 B. rGm (E) 0 C. rGm =0 D.? RGm (E) = T, P (G/.) 6, known as 1000K, (1) CO (g) +1/2 O2 (g) =CO2 (g) K 1 * 1010 =1.659? (2) C (s) +CO2 (g) =2CO (g) K =1.719? Then the reaction of C (s) +1/2 O2 (g) =CO (g) K (3) for? A.9.651 x 1010 B.1.036 x 1010 C.4.731 * 1010 D.2.852 * 1010 8, the response of the delta rGm, =a-bT (a, B is greater than zero), the following statement is correct () The rising temperature of A. is favorable to the reaction, the positive temperature of B. decreases, and the temperature of K increases The effect of C. temperature on the equilibrium can not be determined. The decrease of D. temperature is beneficial to the positive reaction A rGm 9, when a chemical reaction (E) must be less than zero () A. is proceeding spontaneously, B. is spontaneous, C. is in equilibrium, and D. is not certain 12, under the total pressure of 350K and 100kPa, the following ideal gas reactions (...) 1 PCl5 (g) =PCl3 (g) +Cl2 (g) H2 (g) +Cl2 (g) =2HCl