氧化锌填充pa6制备绝缘导热塑料的研究 study of insulating and thermal conductive pa6 plastic filled by zinc oxide.pdfVIP

30 林俊辉等：氧化锌填充PA6 制备绝缘导热塑料的研究 绝缘材料 2013 ，46(4) 氧化锌填充PA6 制备绝缘导热塑料的研究 林俊辉，姜宏伟 （华南理工大学 材料科学与工程学院，广州 510640） 摘要：采用十六烷基三甲氧基硅烷对亚微米氧化锌粉体进行表面有机化改性，将此改性氧化锌与PA6 复合制 得导热PA6 塑料，并对其性能进行研究。结果表明：改性后氧化锌粉体的吸油值比改性前降低了67% ；改性氧 化锌粉体在PA6 树脂基体中分散均匀，PA6 表现出良好的熔体流动性；当添加改性氧化锌的体积分数为25% 时，PA6 塑料表现出良好的导热性和绝缘性，其热导率达到1.05 W/(m ·K) ，体积电阻率为7.29×1010 Ω·m 。 关键词：PA6 塑料；氧化锌；热导率；绝缘 + 中图分类号：TM215. 3 文献标志码：A 文章编号：1009-9239（2013 ）04-0030-05 Study of Insulating and Thermal Conductive PA6 Plastic Filled by Zinc Oxide Lin Junhui, Jiang Hongwei (College of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China) Abstract: A submicron zinc oxide powder was modified by hexadecyltrimethoxysilane, and a thermal con- ductive PA6 plastic was prepared by the modified zinc oxide and PA6, and its properties were studied. The results show that the oil absorption value of the modified zinc oxide decreases by 67% compared to the unmodified powder. The modified zinc oxide is well distributed in the PA6 matrix, and the PA6 plas- tic show good melt flowability. When the volume fraction of the modified zinc oxide is 25%, the PA6 plastic show good thermal conductive and insulating properties, with the thermal conductivity of 1.05 W/ (m ·K) and the volume resistivity of 7.29×1010 Ω·m. Key words: PA6 plastic; zinc oxide; thermal conductivity; insulating 0 引 言 用绝缘性的导热粉体主要有氮化铝和氧化镁，虽然 绝缘性导热聚合物复合材料由于具有有机高 两者在绝缘性和导热性上可满足一些应用要求，但 分子材料的优点，同时克