基体材料对锌(合金)层初始过程的理论研究.doc

基体材料对锌（合金）层初始过程的理论研究摘 要 浸锌是铝及其合金特殊前处理中较为常见的方式，能使铝基体表面获得结合力良好的镀层。但随着结合力要求的提高，仅从浸锌工艺上研究很难取得重大突破。本文从研究铝上浸锌机理出发，描述了浸锌过程的反应机理及基体材料对锌（合金）层初始过程影响的理论基础——电结晶。说明了铝上浸锌是腐蚀—沉积电化学过程，在浸锌过程中，铝上异种金属的存在不仅能作为微阴极使铝基体表面获得较好的腐蚀形貌而且能成为锌的结晶中心对锌的电结晶具有良好催化作用。本研究采用电化学工作站、充放电仪等仪器，通过阴极极化曲线和时间-电位曲线及充放电曲线的测试，原位跟踪了异种金属上锌析出反应的全过程。并对实验的结果进行了分析和讨论，证实了异种金属对锌结晶的具有催化作用能成为锌电结晶中心的基本观点。 关键词：浸锌；电结晶；催化机理；异种金属 THE STUDY OF BASE MATERIAL FOR ZINC (ALLOY) LAYERS INITIAL PROCESS ABSTRACT Dip Zinc is more common in special pre-treatment of aluminum and its alloys，which can bring a good coating to aluminum . However, with the bonding requirements to improve, Studied only from dip Zinc the process is difficult to achieve a major breakthrough. This article start from the mechanism of zinc dipping，describes reaction mechanism of the galvanizing process and the theoretical basis of base material affecting the initial Process of zinc (alloy) layer ——electric crystal. Zinc dipping on aluminum is a Corrosion deposits process , which the existence of dissimilar metals in aluminum not only can induce a better corrosion morphology to aluminum surface as a micro-cathode but also urge electric crystals of zinc as electric crystal center. The open circuit potential - time curves and cathodic polarization curves and Charge-discharge curve were tested by electrochemical workstation Charge and discharge apparatus to track the reaction process of zinc immersion .at the same time experimental results were analyzed and discussed. The results confirms our fundamental point of view KEY WORDS Zinc dipping,electric crystal,Catalytic mechanism,Dissimilar metal 目录 摘 要 I ABSTRACT II 1 引言 1 1.1概述 1 1.2浸锌工艺的研究 1 1.3浸锌的机理的研究现状 2 1.4“电位活化”与金属初始过程的电沉积 2 1.5电结晶理论研究的发展 3 1.6课题提出背景和基本观点 4 2 实验部分 6 2.1不同基体材料在浸锌液中的阴极极化曲线的测定 6 2.1.1实验原理 6 2.1.2实验仪器及药品 6 2.1.3实验所用材料 7 2.1.4实验所需溶液的配制 7 2.1.5研究电极的前处理与浸锌 8 2.1.6实验结果与讨论 10 2.2短路电流实验 12 2.2.1实验原理 12 2.2.2实验仪器及药品 14 2.2.3实验结果与讨论 14 2.3 恒电流放电实验 15 2.3.1实验原理 15 2.3.2实验仪器及药品 16 2.3.3实验结果与讨论 16 2.4 活化对浸