高废物利用（High utilization of waste）.docVIP

高废物利用（High utilization of waste） (1) high boiling silane pyrolysis system. Foreign silicone company mainly uses the method of pyrolysis of silane monomer, solve the problem of high boiling residue. (a) high temperature pyrolysis method. Pyrolysis is at 300-900 DEG C under the condition of high temperature, high Si-Si bond breaks the azeotrope, to silane monomer. This method has the advantages of raw material requirements loose, do not need to remove some impurities high boiling substances in these impurities may catalyst poisoning), silane (catalyst cracking can be all different types for different types of silane effect better. The disadvantage is high reaction temperature, carbondeposition. Continuous high temperature pyrolysis process by German Wacker company, in 300-800 under high temperature, the high boiling and hydrogen chloride in a reaction cracking tube reactor rotating parts in silane monomer. The rotary parts can be carbon and solids removed from the reactor wall, preventing reaction tube blockage. When the temperature is 550 degrees centigrade, the mass fraction of pyrolysis products of methyl chlorosilane in three mass fraction of 32%, two and two for 33% methyl chlorosilane. (b) catalytic pyrolysis method. Shin-Etsu company adopts the tower reactor, using organic amine as catalyst at 80-140 DEG C to high boiling and hydrogen chloride was prepared by the reaction of silane monomer. This technology has the advantages of continuous reaction, mature technology, simple reaction conditions, the catalyst for chlorine loose, high component easy cracking. The disadvantage is a large amount of catalyst cracking, not all components, especially the rich two alkyl silane. The United States DowCorning company aluminum chloride in the presence of catalyst, reaction temperature 300-500, pressure MPa (4-7), the high boiling point compounds and organic chlorosilane mixtures with hydrogen or hydrogen chloride was prepared by the reaction of silane monomer. The character