物理化学答案_上册_高教_第五版（Answer _ _ on physical chemistry of higher education _ Fifth Edition）.docVIP

下载本文档

12
0
约 42页
2017-08-22 发布于河南
举报
版权申诉

物理化学答案_上册_高教_第五版（Answer _ _ on physical chemistry of higher education _ Fifth Edition）.doc

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

物理化学答案_上册_高教_第五版（Answer _ _ on physical chemistry of higher education _ Fifth Edition）

物理化学答案_上册_高教_第五版（Answer _ _ on physical chemistry of higher education _ Fifth Edition） system Water vapor partial pressure of 101.325 kPa, so the total pressure system Page The second chapter of the first law of thermodynamics 2.5 the initial state is 25 ~ C, 200 kPa, 5 mol of an ideal gas, by way of a, B two different ways to the same final. Via a after adiabatic expansion to -28.47 DEG C, 100 kPa, step function Then the constant pressure heating; 200 kPa the final step of heat . B for constant heating process. For the way of B and . Solution: first determine the initial and final system The way of B, which is According to the first law of thermodynamics An ideal gas of 2.64 mol, a temperature rise of 20 C for The value of. Solution: according to the definition of enthalpy 2.102 mol an ideal gas, . From the initial state of 100 kPa, 50 DM Three First, constant volume heating makes the pressure volume increase Up to 150 DM Three Then, the constant pressure cooling to reduce the volume to 25 DM Three . For the whole process . The solution process is illustrated as follows: Page Because Then, For an ideal gas. and Is a function of temperature The only way to constant volume and constant pressure process, so it is convenient to calculate work According to the first law of thermodynamics The 2.13 known 20 DEG C liquid ethanol (C2H5OH, l) of the expansion coefficient The isothermal compression rate. Density. And the molar heat capacity at constant pressure . For 20 ~ C, liquid ethanol . Solution: the second law of thermodynamics can prove that constant pressure molar heat capacity and constant volume molar heat capacity has the following relations The 2.14 volume is 27 m Three There is a small heating device of the insulated container, the wall has a hole with 100 kPa atmosphere, In order to maintain a constant air pressure vessel. This is made using a heating device in the air by 0 DEG C heated to 20 DEG C to ask for How to heat the air inside the container. The air is