高效液相色谱-氢化物发生原子荧光联用法检测不同基质食品中的砷.PDF

7 3 Vol. 7 No. 3 2016 3 Journal of Food Safety and Quality Mar. , 2016 - 1 2 1 1 1 1* 董 喆 , 高明义 , 李梦怡 , 张会亮 , 张庆生 , 曹 进 (1. , 100050; 2. , 100085) 摘 要: 目的 - 方法 HNO3(0.15 mol/L) , , - 结果 0.23~4.68 mg/kg, 0~3.9 mg/kg2 : (DMA)(AsB); : As(III)(DMA)As(V) 结论 , , , 关键词: ; ; -- Determination of arsenic content and speciation in foods of different matrixes by high performance liquid chromatography-hydride generation atomic fluorescence spectrometry 1 2 1 1 1 1* DONG Zhe , GAO Ming-Yi , LI Meng-Yi , ZHANG Hui-Liang , ZHANG Qing-Sheng , CAO Jin (1. National Institutes for Food and Drug Control , Beijing 100050, China; 2. Beijing Purkinje General Instrument Ltd , Beijing 100085, China) ABSTRACT: Objective To establish a method for the determination of total arsenic and chemical speciation in prawn, tuna, shrimp sauce, rice and spinach of different matrixes by high performance liquid chromatography-hydride generation atomic fluorescence spectrometry(HPLC-HG-AFS). Methods After extracting the samples with HNO3 (0.15 mol/L),