生物质热解过程中碱及碱土金属迁徙规律研究-中国电机工程学报.PDF

第33 卷 第26 期 中 国 电 机 工 程 学 报 Vol.33 No.26 Sep.15, 2013 48 2013 年9 月15 日 Proceedings of the CSEE ©2013 Chin.Soc.for Elec.Eng. 文章编号：0258-8013 (2013) 26-0048-06 中图分类号：TK 6 文献标志码：A 学科分类号：470·20 生物质热解过程中碱及碱土金属迁徙规律研究 杜胜磊，杨海平，钱柯贞，姚丁丁，王贤华，陈汉平 (煤燃烧国家重点实验室(华中科技大学) ，湖北省 武汉市 430074) Releasing Behavior of Alkali and Alkaline Earth Metals During Biomass Pyrolysis DU Shenglei, YANG Haiping, QIAN Kezhen, YAO Dingding, WANG Xianhua, CHEN Hanping (State Key Laboratory of Coal Combustion (Huazhong University of Science and Technology), Wuhan 430074, Hubei Province, China) ABSTRACT: The releasing characteristics of alkali and 集量与Cl 存在明显的相关性。在焦炭的外表面，钾元素主 alkaline earth metals (AAEMs) during biomass pyrolysis 要以硅酸盐形式存在，在焦炭的内表面，则主要以氯化钾形 process were explored in a fixed bed reactor, and the 式存在。 enrichment of related inorganic elements inside and outside 关键词：生物质；热解；碱及碱土金属；迁徙；扫描电镜– char particle surfaces was also researched using scanning 能谱分析 electron microscope combined with energy-dispersive X-ray analytical system (SEM/EDX). It is found that the releasing 0 引言 amount of K at high temperature range increases obviously and is affected by the K adsorption capacity of char and the content 随着煤等化石能源供应日趋紧张和能源多元 of Si. The releasing proportion of Na is larger than K due to its 化的发展趋势，储量巨大的生物质资源的开发与利 weaker binding ability with char. The release of calcium and 用越来越得到人们的关注[1] 。生物质资源的热化学 magnesium is mainly because of the decomposition of organic 利用与转化可以有效地减少化石能源利用带来的 calcium and magnesium compon