electrocatalytic activity for co, meoh, and etoh oxidation on the surface of pt-ru nanoparticles supported by metal oxideelectrocatalytic活动公司、甲醇和etoh表面氧化pt-ru纳米金属氧化物的支持.pdfVIP

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electrocatalytic activity for co, meoh, and etoh oxidation on the surface of pt-ru nanoparticles supported by metal oxideelectrocatalytic活动公司、甲醇和etoh表面氧化pt-ru纳米金属氧化物的支持.pdf

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electrocatalytic activity for co, meoh, and etoh oxidation on the surface of pt-ru nanoparticles supported by metal oxideelectrocatalytic活动公司、甲醇和etoh表面氧化pt-ru纳米金属氧化物的支持

Hindawi Publishing Corporation Journal of Nanomaterials Volume 2011, Article ID 614983, 8 pages doi:10.1155/2011/614983 Research Article Electrocatalytic Activity for CO, MeOH, and EtOH Oxidation on the Surface of Pt-Ru Nanoparticles Supported by Metal Oxide Kwang-Sik Sim, Sin-Mook Lim, Hai-Doo Kwen, and Seong-Ho Choi Department of Chemistry, Hannam University, Daejeon 305-811, Republic of Korea Correspondence should be addressed to Seong-Ho Choi, shchoi@hnu.kr Received 15 June 2011; Accepted 14 September 2011 Academic Editor: Steve Acquah Copyright © 2011 Kwang-Sik Sim et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. This paper describes the electrocatalytic activity for CO, MeOH, and EtOH oxidation on the surface of Pt-Ru nanoparticles supported by metal oxide (Nb-TiO -H) prepared for use in a fuel cell. To prepare Nb-TiO -supported Pt-Ru nanoparticles, 2 2 ﬁrst, the Nb-TiO2 supports were prepared by sol-gel reaction of titanium tetraisopropoxide with a small amount of the niobium ethoxide in polystyrene (PS) colloids. Second, Pt-Ru nanoparticles were then deposited by chemical reduction of the Pt4+ and Ru3+ ions onto Nb-TiO supports (Pt-Ru@Nb-TiO -CS). Nb element was used to reduce electrical resistance to facilitate electron 2 2 transport during the electrochemical reactions on a fuel cell electrode. Finally, the Pt-Ru@Nb-TiO2 -H catalysts were formed by the