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assembly of oligoglycine layers on mica surface在云母表面组装oligoglycine层
Journal of Biomaterials and Nanobiotechnology, 2011, 2, 91-97
doi:10.4236/jbnb.2011.21012 Published Online January 2011 (http://www.SciRP.org/journal/jbnb)
Assembly of Oligoglycine Layers on Mica Surface*
1 1 1 1
Svetlana V. Tsygankova , Alexander A. Chinarev , Alexander B. Tuzikov , Ilya S. Zaitsev ,
Nikolai Severin2 3 2 1*
, Alexey A. Kalachev , Jurgen P. Rabe , Nicolai V. Bovin
1Shemyakin-Ovchinnikov Institute of Bioorganic Chemistry, Moscow, Russia; 2Department of Physics, Humboldt University Berlin,
Berlin, Germany; 3Plasmachem GmbH, Berlin, Germany.
Email: bovin@carb.ibch.ru
Received October 7th, 2010; revised November 10th, 2010; accepted December 20th, 2010.
ABSTRACT
Assembly of [Gly -NHCH -] C, [Gly -NHCH -] C CH and [Gly NH(CH ) -] peptides on mica surface in aqueous so-
7 2 4 7 2 3 3 4 2 5 2
lution was studied. The peptides are capable of forming atomically smooth (2.65-4.3 nm in height) layers assembled as
polyglycine II. Monomers in the layers are situated normally to the surface. Formation of analogous flat 2D structures
also takes place in solution but much more slowly than on mica surface, i.e. negatively charged surface plays an active
role promoting the assembly.
Keywords: Self-Assembling, Oligoglycine, Scanning Force Microscopy, Monolayers
1. Introduction tectomers have a band pattern consistent to that of crys-
talline polyglycine II. We analyzed conceivable ways of
Self-assembly of small molecules on solid surface is an
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