calculation of thermal pressure coefficient of dense c15h32, c17h36, c18h38 and c19h40 using pvt data热压力系数的计算密集的c15h32,c17h36 c18h38和c19h40使用pvt数据.pdfVIP

Journal of Modern Physics, 2012, 3, 1763-1770 /10.4236/jmp.2012.311219 Published Online November 2012 (http://www.SciRP.org/journal/jmp) Calculation of Thermal Pressure Coefficient of Dense C15H32, C17H36, C18H38 and C19H40 Using pVT Data * Vahid Moeini , Abol Ghasem Mahdianfar Department of Chemistry, Payame Noor University, Tehran, Iran * Email: v_moeini@ Received August 31, 2012; revised October 2, 2012; accepted October 15, 2012 ABSTRACT The thermal pressure coefficients in liquid n-Pentadecane (C15), n-Heptadecane (C17), n-octadecane (C18) and n-non- adecane (C19) was measured using pVT data. The measurements were carried out at pressures up to 150 MPa in the temperature range from 293 to 383 K. The experimental results have been used to evaluate various thermophysical properties such as thermal pressure coefficients up to 150 MPa with the use of density and temperature data at various pressures. New parameters of the linear isotherm regularity, the so-called LIR equation of state, are used to calculate of thermal pressure coefficients of n-Pentadecane (C15), n-Heptadecane (C17), n-octadecane (C18) and n-nonadecane (C19) dense fluids. In this paper, temperature dependency of linear isotherm regularity parameters in the form of a first order has been developed to second and third order and their temperature derivatives of new parameters are used to calculate thermal pressure coefficients. The resulting model predicts accurately thermal pressure coefficients from the lower density limit at the Boyle density at the from triple temperature up to about double the Boyle temperature.