chemical and microbiological hydrolysis of epoxides of acetylene series环氧化合物的化学和微生物水解乙炔系列.pdfVIP

International Journal of Organic Chemistry, 2011, 1, 113-118 doi:10.4236/ijoc.2011.13017 Published Online September 2011 (http://www.SciRP.org/journal/ijoc) Chemical and Microbiological Hydrolysis of Epoxides of Acetylene Series 1* 2 2 Mammad Veliyev , Mammad Salmanov , Saida Aliyeva , 1 2 Mahruza Shatirova , Gulnara Yagubova 1 Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Baku, Azerbaijan 2Institute of Microbiology of Azerbaijan National Academy of Sciences, Baku, Azerbaijan * E-mail : mveliyev@mail.ru Received July 21, 2011; revised August 25, 2011; accepted September 3, 2011 Abstract The chemical and microbiological hydrolyses of epoxide compounds of acetylene series have been compara- tively carried out. It has been shown that as distinguished from chemical one in microbiological hydrolysis along with corresponding optically active glycols, ketoalcohols of acetylene series are also formed. It has been also defined that the synthesized glycols of acetylene series have bactericide properties related to sul- fate-reducing bacteria at concentration of 100 - 200 mg/l. It has been established that an introduction of elec- tron-acceptor chlorine atoms in molecules influence on decreasing of bactericide activity of acetylene gly- cols. Keywords: Hydrolyze, Glycols, Epoxide, Ketoalcohols, Acetylene 1. Introduction chemical synthe