chemically modified carbon paste electrode for determination of cesium ion by potentiometric method化学修饰碳糊电极测定铯离子电位法.pdfVIP

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chemically modified carbon paste electrode for determination of cesium ion by potentiometric method化学修饰碳糊电极测定铯离子电位法.pdf

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chemically modified carbon paste electrode for determination of cesium ion by potentiometric method化学修饰碳糊电极测定铯离子电位法

American Journal of Analytical Chemistry , 2012, 3, 576-586 /10.4236/ajac.2012.38076 Published Online August 2012 (http://www.SciRP.org/journal/ajac) Chemically Modified Carbon Paste Electrode for Determination of Cesium Ion by Potentiometric Method 1* 2 2 Refat F. Aglan , Gehad G. Mohamed , Hala A. Mohamed 1Hot Laboratories Center, Atomic Energy Authority, Cairo, Egypt 2Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt * Email: refatfekry_aglan@ Received June 19, 2012; revised July 20, 2012; accepted July 29, 2012 ABSTRACT A new chemically modified carbon paste electrode for cesium(I) ion determination based on potassium zinc hexacyan- oferrate (PZHCF) as an ionophore was prepared. The electrode exhibits a Nernstian response for Cs(I) ions over a wide concentration range from 1 × 10–6 to 1 × 10–1 mol·L–1 with a slope of 58 ± 0.5 mV·decade–1 . It has a response time of about 35 s and can be used for a period of 3 months with good reproducibility. Detection limit obtained in the optimal conditions was 3 × 10–7 mol·L–1 . The potentiometric response is independent of the pH of the solution in the pH range 4.0 - 8.0. The electrode possesses the advantages of low resistance, fast response over a variety of other cations. The proposed electrode is applied as a sensor for the determination of Cs(I) ion concentration in different samples solutions. The results showed a good correlation with the data obtained by atomic absorption spectrometric method. Keywords: Cesium Determination; Modified Ion Selective Electrode; Potassium Zinc Hexacyanoferrate Ionoph