cu(ii) extraction in ionic liquids and chlorinated solvents temperature effect铜(ii)以离子液体为溶剂的提取以及氯化溶剂温度效应.pdfVIP

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cu(ii) extraction in ionic liquids and chlorinated solvents temperature effect铜(ii)以离子液体为溶剂的提取以及氯化溶剂温度效应.pdf

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cu(ii) extraction in ionic liquids and chlorinated solvents temperature effect铜(ii)以离子液体为溶剂的提取以及氯化溶剂温度效应

Green and Sustainable Chemistry, 2011, 1, 155-164 doi:10.4236/gsc.2011.14024 Published Online November 2011 (http://www.SciRP.org/journal/gsc) Cu(II) Extraction in Ionic Liquids and Chlorinated Solvents: Temperature Effect 1* 2 2* 1 1 Raimondo Germani , Maria V. Mancini , Nicoletta Spreti , Pietro Di Profio , Gianfranco Savelli 1CEMIN, Center of Excellence on Innovative Nanostructured Materials, Department of Chemistry, University of Perugia, Perugia, Italy 2Department of Chemistry, Chemical Engineering and Materials, University of L’Aquila , L ’Aquila , Italy * E-mail : spreti@univaq.it Received July 7, 2011; revised August 17, 2011; accepted August 28, 2011 Abstract Room temperature ionic liquids have been currently used in liquid/liquid extraction processes in order to substitute conventional organic solvents. In this paper, a series of chlorinated solvents and 1-alkyl-3-me- thylimidazolium-based ionic liquids were selected to study the extraction efficiency of a lipophilic polya- mine 1,1,7,7-tetraethyl-4-tetradecyldiethylenetriamine (TE14DT) towards the model ion Cu(II) in such dif- ferent media. The effect of temperature on the extraction efficiency was also investigated. The metal ion par- tition was found to be strongly dependent on both the nature of the solvent and on the working temperature. The viscosity of ionic liquids and the water content in ionic liquid were found to affect the extraction effi- ciency of TE14DT. The chemical nature of