原创力文档determination of optimum conditions for x-ray fluorescence analysis using coupling equations确定最佳条件使用的x射线荧光分析耦合方程.pdfVIP
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determination of optimum conditions for x-ray fluorescence analysis using coupling equations确定最佳条件使用的x射线荧光分析耦合方程
Journal of Analytical Sciences, Methods and Instrumentation, 2012, 2, 81-86 81
/10.4236/jasmi.2012.22015 Published Online June 2012 (http://www.SciRP.org/journal/jasmi)
Determination of Optimum Conditions for X-Ray
Fluorescence Analysis Using Coupling Equations
1 2* 3
Antonina Nikonovna Smagunova , Oyuntsetseg Bolormaa , Sergei Dimitrovich Pan’kov
1Irkutsk State University, Irkutsk, Russia; 2National University of Mongolia, UlaanBaatar, Mongolia; 3SibVAMI, Irkutsk, Rus-
sia.
*
Email: bolormuis@
Received March 29th, 2012; revised April 24th, 2012; accepted May 5th, 2012
ABSTRACT
Coupling equations used to calculate the chemical composition of substances by X-ray fluorescence analysis can be
classified as empirical, theoretical or semi-empirical based on the method for determining the coefficients of the cali-
bration function. The advantages and disadvantages of each class of equations are discussed. Recommendations for the
selecting the optimum conditions for determining empirical correction coefficients and their control during analysis are
provided.
Keywords: X-Ray Fluorescence Analysis; Coupling Equation; Optimum Condition; Calibration; Reference Samples
1. Introduction tion coefficients, the coupling equations can be empirical,
theoretical or semi-empirical [7].
In the field of X-ray fluorescence analysis (XRF) calibra-
The aim of the paper is to examine the various algo-
tion functions that relate the concentration of the element
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